PARTIAL OXIDATION OF METHANE BY NITROUS OXIDE OVER MOLYBDENUM ON SILICA
作者： H. F. Liu , R. S. Liu , K. Y. Liew , R. E. Johnson , J. H. Lunsford
DOI: 10.1021/JA00327A009
关键词:
摘要: Kinetic data are presented for the partial oxidation of methane to methanol and formaldehyde by nitrous oxide catalysed molybdenum supported on silica when steam is present in system. The used as evidence show how selective mechanism fits into an overall reaction scheme. Moreover, support this mechanism, spectroscopic given formation methyl radicals methoxide ions surface. 12 references, 7 figures, 1 table.
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