Semi-ideal solution theory. 2. Extension to conductivity of mixed electrolyte solutions.
作者： Yu-Feng Hu , Xian-Ming Zhang , Ji-Guang Li , Qian-Qing Liang
DOI: 10.1021/JP805833G
关键词:
摘要: Conductivities were measured for the ternary systems NaCl−LaCl3−H2O and KCl−CdCl2−H2O their binary subsystems NaCl−H2O, KCl−H2O, CdCl2−H2O, LaCl3−H2O at 298.15 K. The semi-ideal solution theory thermodynamic properties of aqueous solutions electrolyte mixtures was used together with Eyring absolute rate to study conductivity mixed solutions. A novel simple equation prediction in terms data established. conductivities those reported literature test newly established generalized Young’s rule comparison results show that deviation a from new is closely related its isopiestic behavior deviations are often within experimental uncertainty if examined system obeys linear relation. While larger...
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