Palladium-Catalyzed Addition of Dialkylamines to Linalyl Acetate and Related Compounds
作者： S. Watanabe , T. Fujita , M. Sakamoto , T. Haga , T. Kuramochi
DOI: 10.1080/10412905.1997.9700745
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摘要: Abstract Pd(PPh3)4 catalyzed reaction of linalyl acetate with diethylamine gave N, N-diethylgeranylamine as a main product (E:Z = 90:10). The various amines their corresponding products. For example, the aniline N-geranylaniline in 100% stereoselectivity. methylcarbonate using Pd(0) catalyst similarly 92:8).
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