Use of Electron Paramagnetic Resonance for Investigating Glasses and Raw Materials (Review)
作者： L. D. Bogomolova , V. A. Zhachkin , T. K. Pavlushkina
DOI: 10.1007/S10717-015-9737-Z
关键词:
摘要: It is shown that electron paramagnetic resonance can be used to study the fine structure of glasses and glass enamel materials as well find identify defects in glass. The spectra ions (Cu2+, V4+, Ti3+, Mo5+ Mn2+, Fe3+ ) are discussed. Specific examples detection these sitals, which they introduced surface-active additives or present impurities entering crystallized via raw materials, examined. determined most informative for studying phase separation Cu2+ V4+.
springer.com
sci-hub.se 参考文章(10)
Thomas P. Seward, Immiscibility and Microstructure in Amorphous Borates Borate Glasses. pp. 427- 443 ,(1978) , 10.1007/978-1-4684-3357-9_22
R. R. SHAW, D. R. UHLMANN, Subliquidus Immiscibility in Binary Alkali Borates Journal of the American Ceramic Society. ,vol. 51, pp. 377- 382 ,(1968) , 10.1111/J.1151-2916.1968.TB11897.X
D.L. Griscom, Electron spin resonance in glasses Journal of Non-Crystalline Solids. ,vol. 40, pp. 211- 272 ,(1980) , 10.1016/0022-3093(80)90105-2
H. Kawazoe, H. Hosono, T. Kanazawa, Electronic structure and properties of oxide glasses (II) Basicity measured by copper(II) ion probe in Na2OP2O5, K2OB2O3 and K2SO4ZnSO4 glasses Journal of Non-crystalline Solids. ,vol. 29, pp. 173- 186 ,(1978) , 10.1016/0022-3093(78)90112-6
L.D. Bogomolova, V.A. Jachkin, N.A. Krasil'nikova, EPR study of vanadium-containing amorphous silica formed by sol–gel method Journal of Non-crystalline Solids. ,vol. 241, pp. 13- 26 ,(1998) , 10.1016/S0022-3093(98)00745-5
L.D. Bogomolova, A.G. Fedorov, M.E. Kubrinskaya, EPR and optical study of copper diffusion layers produced by ion exchange in binary alkali-silicate glasses Journal of Non-crystalline Solids. ,vol. 54, pp. 153- 161 ,(1983) , 10.1016/0022-3093(83)90089-3
L.D Bogomolova, T.F Dolgolenko, V.A Tachkin, V.N Lazukin, The EPR of V4+ and Cu2+ ions as a method of the study of glass structure Journal of Magnetic Resonance. ,vol. 15, pp. 283- 291 ,(1974) , 10.1016/0022-2364(74)90081-X
Abdul Hameed, Gokarakonda Ramadevudu, Siddey Laksmisrinivasa Rao, Mohmmad Shareefuddin, Mudumba Narasimha Chary, Electron Paramagnetic Resonance Studies of Cu2+ and VO2+ Spin Probes in RO-Li2O-Na2O-K2O-B2O3 (R = Zn, Mg, Sr and Ba) Glass Systems New Journal of Glass and Ceramics. ,vol. 02, pp. 51- 58 ,(2012) , 10.4236/NJGC.2012.21008
R. H. Sands, Paramagnetic Resonance Absorption in Glass Physical Review. ,vol. 99, pp. 1222- 1226 ,(1955) , 10.1103/PHYSREV.99.1222
F. Gonella, F. Caccavale, L.D. Bogomolova, V.A. Jachkin, Application of electron paramagnetic resonance to the study of Cu2+ ions in Cu-Na ion-exchanged glasses Applied Physics A. ,vol. 68, pp. 539- 546 ,(1999) , 10.1007/S003390050937