Superposition-Additive Approach: Clusterization Thermodynamic Parameters of Bifunctional Nonionic Amphiphiles at the Air/Water Interface

摘要: The superposition-additive approach developed and tested previously on monofunctional nonionic amphiphiles is updated used for the calculation of thermodynamic clusterization parameters with two functional groups. In framework this formation three classes bifunctional were calculated using corresponding data amphiphiles. example 2-hydroxycarboxylic acids, α-amino alkyl amides it was shown that regarded adequately reproduces parameter values without direct use quantum chemical calculations. It exploits rather only or experimental existing systematic errors description can be attributed to incomplete reproduction in...