Dy3+- and Eu3+-doped LaGaO3 nanocrystalline phosphors for field emission displays

作者: Xiaoming Liu , Jun Lin

DOI: 10.1063/1.2400092

关键词:

摘要: Nanocyrstalline LaGaO3 and Dy3+- Eu3+-doped were prepared through a Pechini-type sol-gel process. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), photoluminescence, cathodoluminescence spectra, lifetimes utilized to characterize the samples. XRD reveals that samples begin crystallize at 900°C pure phase can be obtained 1000°C. FE-SEM images indicate are both composed of aggregated spherical particles with sizes ranging from 40to80nm. Under excitation ultraviolet light low voltage beams (1–5kV), undoped sample shows strong blue peaking 433nm, show their characteristic emissions Dy3+ (F9∕24-H15∕26 F9∕24-H13∕26 transitions) Eu3+ (D0,1,25-F1,2,3,47 transitions), respectively. The relevant luminescence mechanisms discussed.

参考文章(26)
S. H. M. Poort, D. Cetin, A. Meijerink, G. Blasse, The Luminescence of Mn2 + ‐Activated ZnGa2 O 4 Journal of The Electrochemical Society. ,vol. 144, pp. 2179- 2183 ,(1997) , 10.1149/1.1837761
W. Y. Shen, M. L. Pang, J. Lin, J. Fang, Host-Sensitized Luminescence of Dy3 + in Nanocrystalline β ­ Ga2 O 3 Prepared by a Pechini-Type Sol-Gel Process Journal of The Electrochemical Society. ,vol. 152, ,(2005) , 10.1149/1.1847674
M. Yu, J. Lin, J. Fu, H. J. Zhang, Y. C. Han, Sol–gel synthesis and photoluminescent properties of LaPO4:A (A = Eu3+, Ce3+, Tb3+) nanocrystalline thin films J. Mater. Chem.. ,vol. 13, pp. 1413- 1419 ,(2003) , 10.1039/B302600K
A Durygin, A Suchocki, L Arizmendi, M Berkowski, Spectroscopy of defect centers in LaGaO3 crystals Journal of Alloys and Compounds. ,vol. 323, pp. 696- 700 ,(2001) , 10.1016/S0925-8388(01)01041-6
W Marti, P Fischer, F Altorfer, H J Scheel, M Tadin, Crystal structures and phase transitions of orthorhombic and rhombohedral RGaO3 (R=La,Pr,Nd) investigated by neutron powder diffraction Journal of Physics: Condensed Matter. ,vol. 6, pp. 127- 135 ,(1994) , 10.1088/0953-8984/6/1/014
G. Koren, A. Gupta, E. A. Giess, A. Segmüller, R. B. Laibowitz, Epitaxial films of YBa2Cu3O7−δon NdGaO3, LaGaO3, and SrTiO3substrates deposited by laser ablation Applied Physics Letters. ,vol. 54, pp. 1054- 1056 ,(1989) , 10.1063/1.101559
In-Keun Jeong, Hong Lee Park, Sun-il Mho, Two self-activated optical centers of blue emission in zinc gallate Solid State Communications. ,vol. 105, pp. 179- 183 ,(1998) , 10.1016/S0038-1098(97)10101-6
M. Yu, J. Lin, Z. Wang, J. Fu, S. Wang, H. J. Zhang, Y. C. Han, Fabrication, Patterning, and Optical Properties of Nanocrystalline YVO4:A (A = Eu3+, Dy3+, Sm3+, Er3+) Phosphor Films via Sol−Gel Soft Lithography Chemistry of Materials. ,vol. 14, pp. 2224- 2231 ,(2002) , 10.1021/CM011663Y