Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkenes Using Nucleophilic CF3SiMe3: Efficient C(sp3)–CF3 Bond Formation
作者： Lingling Chu , Feng-Ling Qing
DOI: 10.1021/OL300639A
关键词:
摘要: An efficient C(sp3)–CF3 bond-forming reaction via Cu-catalyzed oxidative trifluoromethylation of terminal alkenes has been developed, which proceeds under mild conditions using readily available, less expensive CF3SiMe3 as the source CF3 group. This method allows access to a variety trifluoromethylated allylic compounds.
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