Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.
作者： Simon J. Byrne , Anthony J. Fletcher , Paul Hebeisen , Michael C. Willis
DOI: 10.1039/B923186B
关键词:
摘要: A desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted their corresponding monoester derivatives with selectivities of up 96% ee.
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