THE REACTION OF 8,8-DISUBSTITUTED HEPTAFULVENES WITH AMINES IN THE PRESENCE OF COPPER(II) ACETATE

作者: Katsuo Kikuchi , Yuji Maki , Eiko Nomata , Kyoko Tada

DOI: 10.1246/CL.1978.677

关键词:

摘要: The reaction of 8,8-dicyanoheptafulvene (1a) with ammonia and several kinds amines in the presence copper(II) acetate afforded 1,2-dihydro-2-iminocyclohepta[b]pyrrole derivatives (2) and/or 3-aminoisoquinoline (3). 8-cyano-8-methoxycarbonylheptafulvene (1b) has also been described.

参考文章(2)
Tetsuo Nozoe, Toshio Mukai, Kazutoshi Osaka, Nobuyuki Shishido, Synthesis of Some 8, 8-Disubstituted Heptafulvene Derivatives Bulletin of the Chemical Society of Japan. ,vol. 34, pp. 1384- 1390 ,(1961) , 10.1246/BCSJ.34.1384
Hideo Nakao, Nobuo Soma, Genshun Sunagawa, Studies on Seven-membered Ring Compounds. XX. Reactions of Troponeimine Derivatives. (2) Chemical & Pharmaceutical Bulletin. ,vol. 13, pp. 828- 837 ,(1965) , 10.1248/CPB.13.828