Temperature- and composition-driven changes in site occupation of indium solutes in Gd1+3xAl2-3x

作者: Matthew O. Zacate , Gary S. Collins

DOI: 10.1103/PHYSREVB.69.174202

关键词:

摘要: Fractional concentrations of indium solutes at Gd sites and Al in the Laves phase Gd113xAl223x were measured for different temperatures sample compositions using perturbed angular correlation spectroscopy. At fixed composition, fraction on was observed to decrease as temperature increased. temperature, increase composition became more deficient Gd. The trends are explained a thermodynamic model that couples solute site occupation with point defects. enthalpy crystal when switches from an determined be 0.343~7! eV.

参考文章(22)
Patrick Chartier, Mahalingam Balasubramanian, Dale Brewe, Tariq Manzur, Douglas Pease, Joseph Budnick, Li Huang, Chi Law, Scott Russell, Clyde Kimball, Site selectivity in Fe doped β phase NiAl Journal of Applied Physics. ,vol. 75, pp. 3842- 3846 ,(1994) , 10.1063/1.356063
Y.L Hao, R Yang, Y.Y Cui, D Li, The effect of Ti/Al ratio on the site occupancies of alloying elements in γ-TiAl Intermetallics. ,vol. 8, pp. 633- 636 ,(2000) , 10.1016/S0966-9795(99)00138-7
Matthew O. Zacate, Gary S. Collins, Site Preferences of Hyperfine Impurities in Ni 2 Al 3 Phases Hyperfine Interactions. ,vol. 136, pp. 647- 652 ,(2001) , 10.1023/A:1020590909136
P Wodniecki, B Wodniecka, A Kulińska, M Uhrmacher, K.P Lieb, Switching of 111In impurity sites in the HfAl2 lattice Physics Letters A. ,vol. 288, pp. 227- 230 ,(2001) , 10.1016/S0375-9601(01)00556-4
Gary S. Collins, Matthew O. Zacate, Site Preference Model for Hyperfine Impurities in Compounds Hyperfine Interactions. ,vol. 136, pp. 641- 646 ,(2001) , 10.1023/A:1020538925066
H. Jacobi, H.-J. Engell, Defect structure in non-stoichiometric β-(Ni, Cu)Al Acta Metallurgica. ,vol. 19, pp. 701- 711 ,(1971) , 10.1016/0001-6160(71)90025-3
C. Woodward, S. Kajihara, L. H. Yang, Site preferences and formation energies of substitutional Si, Nb, Mo, Ta, and W solid solutions in L 1 0 Ti-Al Physical Review B. ,vol. 57, pp. 13459- 13470 ,(1998) , 10.1103/PHYSREVB.57.13459
Y.P. Wu, N.C. Tso, J.M. Sanchez, J.K. Tien, Modeling of ternary site occupation in L12 ordered intermetallics Acta Metallurgica. ,vol. 37, pp. 2835- 2840 ,(1989) , 10.1016/0001-6160(89)90318-0
A. V. Ruban, H. L. Skriver, Calculated site substitution in ternary γ | I H - Ni 3 Al: Temperature and composition effects Physical Review B. ,vol. 55, pp. 856- 874 ,(1997) , 10.1103/PHYSREVB.55.856
Gary L. Catchen, James M. Adams, Todd M. Rearick, High-temperature partitioning ofprobe181impurities between Li and group-V sites inLiNbO3andLiTaO3 Physical Review B. ,vol. 46, pp. 2743- 2749 ,(1992) , 10.1103/PHYSREVB.46.2743