Effect of Calcination Temperature and Concentration on Luminescence Properties of Novel Ca3Y2Si3O12:Eu Phosphors

作者: Vengala Rao Bandi , Yung‐Tang Nien , Tzung‐Heng Lu , In‐Gann Chen , None

DOI: 10.1111/J.1551-2916.2009.03308.X

关键词:

摘要: In the present work, nanocrystalline Ca 3 Y 2(1-x) Si O 12 :Eu x (x = 1, 5, 10, and 20 mol%) novel phosphors were synthesized by a sol-gel method. The effect of temperature concentration on structural luminescence properties powders investigated under UV excitation. X-ray diffraction profiles showed that all peaks could be attributed to orthorhombic 2 doped Eu phase at various calcination temperatures with concentrations. Scanning electron microscopy was carried out understand surface morphological features grain sizes. Photoluminescence (PL) measurements exhibited presence transitions 3+ dopant, being 5 D 0 _ 7 F transition most intense charge transfer band it observed located around 250 nm. It also found that, PL intensity strongly dependent both dopant concentration. highest for mol% 1000°C. spectral possess sharp bright emission potential applications flat panel displays some other related electronic systems, in observing images red color.

参考文章(15)
N. Lakshminarasimhan, U.V. Varadaraju, Synthesis and Eu3+ luminescence in new oxysilicates, ALa3Bi(SiO4)3O and ALa2Bi2(SiO4)3O [ACa, Sr and Ba] with apatite-related structure Journal of Solid State Chemistry. ,vol. 178, pp. 3284- 3292 ,(2005) , 10.1016/J.JSSC.2005.08.006
Song Ye, Bin Zhu, Jin Luo, Yu Teng, Jingxin Chen, G Lakshminarayana, Guodong Qian, Jianrong Qiu, None, Energy transfer between silicon–oxygen-related defects and Yb3+ in transparent glass ceramics containing Ba2TiSi2O8 nanocrystals Applied Physics Letters. ,vol. 93, pp. 181110- ,(2008) , 10.1063/1.3021086
Yiguo Su, Liping Li, Guangshe Li, Synthesis and Optimum Luminescence of CaWO4-Based Red Phosphors with Codoping of Eu3+ and Na+ Chemistry of Materials. ,vol. 20, pp. 6060- 6067 ,(2008) , 10.1021/CM8014435
Xianping Fan, Minquan Wang, Yi Yu, Qingzhou Wu, Crystallization process of MgSiO3 gel and influence of crystallization on luminescence of Eu3+ ions Journal of Physics and Chemistry of Solids. ,vol. 57, pp. 1259- 1262 ,(1996) , 10.1016/0022-3697(95)00313-4
X.M. Han, J. Lin, M.L. Pang, M. Yu, S.B. Wang, Sol–gel deposition and luminescence properties of lanthanide ion-doped Y2(1-x)Gd2xSiWO8 (0≤x≤1) phosphor films Applied Physics A. ,vol. 80, pp. 1547- 1552 ,(2005) , 10.1007/S00339-004-2506-4
A Potdevin, G Chadeyron, D Boyer, B Caillier, R Mahiou, Sol?gel based YAG?:?Tb3+ or Eu3+ phosphors for application in lighting sources Journal of Physics D. ,vol. 38, pp. 3251- 3260 ,(2005) , 10.1088/0022-3727/38/17/S29
Yu-Chung Chen, Yen-Hwei Chang, Bin-Siang Tsai, Influence of processing conditions on synthesis and photoluminescence of Eu3+-activated strontium stannate phosphors Journal of Alloys and Compounds. ,vol. 398, pp. 256- 260 ,(2005) , 10.1016/J.JALLCOM.2005.02.019
Pingle Zhou, Xibin Yu, Liangzhun Yang, Shiping Yang, Wenjie Gao, Synthesis of Y2Si2O7:Eu nanocrystal and its optical properties Journal of Luminescence. ,vol. 124, pp. 241- 244 ,(2007) , 10.1016/J.JLUMIN.2006.03.002