Electrocatalytic oxidation of sodium borohydride on metal ad-atom modified Au(111) single crystal electrodes in alkaline solution

作者: Şükriye Ulubay Karabiberoğlu , Levent Pelit , Buket Gelmez , Zekerya Dursun

DOI: 10.1016/J.IJHYDENE.2011.06.123

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摘要: Abstract The electrochemical oxidation of borohydride was investigated by using various ad-atom modified Au(111) electrodes in alkaline media comparison to single crystal, polycrystalline Au, Pt and Zn electrodes. catalytic activity gold towards has tended increase more as reflected the peak concentration range NaOH (0.01–2.0 M) studied. Additional shift on potential observed for both negative potentials compared that bare electrodes, respectively. surfaces do not only provide a superior electrical contact, but also accelerates electron transfer proven current positive potential.

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