Conditions for Reversible Na Intercalation in Graphite: Theoretical Studies on the Interplay Among Guest Ions, Solvent, and Graphite Host

作者: Gabin Yoon , Haegyeom Kim , Inchul Park , Kisuk Kang

DOI: 10.1002/AENM.201601519

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摘要: Graphite is the most widely used anode material for Li‐ion batteries and is also considered a promising anode for K‐ion batteries. However, Na+, a similar alkali ion to Li+ or K+, is incapable of being intercalated into graphite and thus, graphite is not considered a potential electrode for Na‐ion batteries. This atypical behavior of Na has drawn considerable attention; however, a clear explanation of its origin has not yet been provided. Herein, through a systematic investigation of alkali metal graphite intercalation compounds (AM …

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