A novel preparation of core-shell electrode materials via evaporation-induced self-assembly of nanoparticles for advanced Li-ion batteries.
作者： Zhiqiang Xie , Sarah Ellis , Wangwang Xu , Dara Dye , Jianqing Zhao
DOI: 10.1039/C5CC05577F
关键词:
摘要: We report, for the first time, a simple and novel synthesis of Li-rich layered-spinel core–shell heterostructure (L@S core–shell) via evaporation-induced self-assembly (EISA) Ni-doped Li4Mn5O12 nanoparticles (Li4Mn4.5Ni0.5O12) onto surface layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 (LMNCO) without using any surfactant during coating process. The resultant L@S as cathode in lithium ion batteries demonstrates significantly improved specific capacity, cycling performance rate capability compared to pristine LMNCO.
rsc.org
lsu.edu 
researchgate.net 
sci-hub.se 参考文章(33)
Haijun Yu, Haoshen Zhou, High-Energy Cathode Materials (Li2MnO3-LiMO2) for Lithium-Ion Batteries. Journal of Physical Chemistry Letters. ,vol. 4, pp. 1268- 1280 ,(2013) , 10.1021/JZ400032V
K.-S. Lee, H.J. Bang, S.-T. Myung, J. Prakash, K. Amine, Y.-K. Sun, Synthesis and electrochemical properties of spherical spinel Li1.05M0.05Mn1.9O4 (M = Mg and Al) as a cathode material for lithium-ion batteries by co-precipitation method Journal of Power Sources. ,vol. 174, pp. 726- 729 ,(2007) , 10.1016/J.JPOWSOUR.2007.06.110
Zhiqiang Xie, Hilary Eikhuemelo, Jianqing Zhao, Carrington Cain, Wangwang Xu, Ying Wang, Ni and Fe Dual-Doped Li4Mn5O12 Spinels as Cathode Materials for High-Voltage Li-Ion Batteries Journal of The Electrochemical Society. ,vol. 162, ,(2015) , 10.1149/2.0601508JES
Min-Sik Park, Jong-Won Lee, Wonchang Choi, Dongmin Im, Seok-Gwang Doo, Kyu-Sung Park, On the surface modifications of high-voltage oxide cathodes for lithium-ion batteries: new insight and significant safety improvement Journal of Materials Chemistry. ,vol. 20, pp. 7208- 7213 ,(2010) , 10.1039/C0JM00617C
Dapeng Wang, Ilias Belharouak, Guangwen Zhou, Khalil Amine, None, Nanoarchitecture Multi-Structural Cathode Materials for High Capacity Lithium Batteries Advanced Functional Materials. ,vol. 23, pp. 1070- 1075 ,(2013) , 10.1002/ADFM.201200536
Taolin Zhao, Shi Chen, Li Li, Xiaofeng Zhang, Renjie Chen, Ilias Belharouak, Feng Wu, Khalil Amine, Synthesis, characterization, and electrochemistry of cathode material Li[Li0.2Co0.13Ni0.13Mn0.54]O2 using organic chelating agents for lithium-ion batteries Journal of Power Sources. ,vol. 228, pp. 206- 213 ,(2013) , 10.1016/J.JPOWSOUR.2012.11.099
A. Robert Armstrong, Michael Holzapfel, Petr Novák, Christopher S. Johnson, Sun-Ho Kang, Michael M. Thackeray, Peter G. Bruce, Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2 Journal of the American Chemical Society. ,vol. 128, pp. 8694- 8698 ,(2006) , 10.1021/JA062027+
Q. Y. Wang, J. Liu, A. Vadivel Murugan, A. Manthiram, High capacity double-layer surface modified Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode with improved rate capability Journal of Materials Chemistry. ,vol. 19, pp. 4965- 4972 ,(2009) , 10.1039/B823506F
Yan Y. Huang, Tuomas P. J. Knowles, Eugene M. Terentjev, Strength of Nanotubes, Filaments, and Nanowires From Sonication-Induced Scission Advanced Materials. ,vol. 21, pp. 3945- 3948 ,(2009) , 10.1002/ADMA.200900498
Karl A. Kusters, Sotiris E. Pratsinis, Steven G. Thoma, Douglas M. Smith, Energy—size reduction laws for ultrasonic fragmentation Powder Technology. ,vol. 80, pp. 253- 263 ,(1994) , 10.1016/0032-5910(94)02852-4