Effect of free-radical release on diesel ignition delay under simulated cold-starting conditions

作者: P.Q.E. Clothier , A. Moise , H.O. Pritchard

DOI: 10.1016/0010-2180(90)90022-J

关键词:

摘要: Abstract Peak compression temperatures typical of those achieved when cranking a cold diesel engine can be produced by running gasoline ratio 7.5, with block temperature 100°C. Under the chosen operating conditions, fuel cetane index 43 would ignite only very feebly, ignition delays in excess about 9 ms, but presence various additives, iso-octyl nitrate, di-tert-butyl peroxide, tert-butyl perbenzoate, 1,1-di-(tert-butylperoxy) cyclohexane, and 3,3,5-trimethyl between 3 7 ms were observed; although thermal decomposition rates these additives span approximately factor 60, do not correlate rates. Some measurements made on effect diethyl ether, either blended or bled into air intake: its efficacy as cold-starting aid stems from fact that etherair mixtures spontaneously during stroke, thereby causing to well.

参考文章(11)
Sidney W. Benson, Kinetics of Pyrolysis of Alkyl Hydroperoxides and Their O–O Bond Dissociation Energies The Journal of Chemical Physics. ,vol. 40, pp. 1007- 1013 ,(1964) , 10.1063/1.1725239
Guenther Von Elbe, Bernard Lewis, Combustion, flames and explosions of gases Academic Press. ,(1961)
Robert R. Jenkins, Free radical chemistry. Relationship to exercise. Sports Medicine. ,vol. 5, pp. 156- 170 ,(1988) , 10.2165/00007256-198805030-00003
D. H. Shaw, H. O. Pritchard, Thermal decomposition of di-tert-butyl peroxide at high pressure Canadian Journal of Chemistry. ,vol. 46, pp. 2721- 2724 ,(1968) , 10.1139/V68-448
H.O. Pritchard, Thermal decomposition of isooctyl nitrate Combustion and Flame. ,vol. 75, pp. 415- 416 ,(1989) , 10.1016/0010-2180(89)90052-7
Huw O. Pritchard, Peter Q. E. Clothier, Anaerobic operation of an internal combustion engine Journal of The Chemical Society, Chemical Communications. pp. 1529- 1530 ,(1987) , 10.1039/C39860001529
C. K. Yip, H. O. Pritchard, Isolation of the initial step in the thermal decomposition of di-tert-butyl peroxide Canadian Journal of Chemistry. ,vol. 47, pp. 4808- 4809 ,(1969) , 10.1139/V69-781
Lok Thang, Huw O. Pritchard, Simulation of thermal explosions in gaseous mixtures Journal of the Chemical Society, Faraday Transactions. ,vol. 84, pp. 1923- 1926 ,(1988) , 10.1039/F29888401923
Peter Q. E. Clothier, John L. Collister, Marsha T. J. Glionna, Huw O. Pritchard, Thermal explosions and the linear mixture rule Journal of the Chemical Society, Faraday Transactions. ,vol. 84, pp. 35- 40 ,(1988) , 10.1039/F29888400035