Luminescent Noble Metal Nanoclusters as an Emerging Optical Probe for Sensor Development

作者: Xun Yuan , Zhentao Luo , Yong Yu , Qiaofeng Yao , Jianping Xie

DOI: 10.1002/ASIA.201201236

关键词:

摘要: In the past few years, highly luminescent noble metal nanoclusters (e.g., Au and Ag NCs or Au/Ag in short) have emerged as a class of promising optical probes for construction high-performance sensors because their ultrasmall size (<2 nm), strong luminescence, good photostability, excellent biocompatibility, unique metal-core@ligand-shell structure. this Focus Review, we briefly summarize common syntheses water-soluble highly-luminescent thiolate- protein-protected interesting luminescence properties, highlight recent progress use with an emphasis on mechanisms underlying selectivity, finally discuss approaches to improving sensitivity. The scope works surveyed is confined NCs.

参考文章(132)
Yael Levi-Kalisman, Pablo D. Jadzinsky, Nir Kalisman, Hironori Tsunoyama, Tatsuya Tsukuda, David A. Bushnell, Roger D. Kornberg, Synthesis and characterization of Au102(p -MBA)44 nanoparticles Journal of the American Chemical Society. ,vol. 133, pp. 2976- 2982 ,(2011) , 10.1021/JA109131W
Bernard Valeur, Mário Nuno Berberan-Santos, Molecular fluorescence : principles and applications Wiley-VCH. ,(2012) , 10.1002/9783527650002
Chen Zhou, Ce Sun, Mengxiao Yu, Yanping Qin, Jinguo Wang, Moon Kim, Jie Zheng, Luminescent Gold Nanoparticles with Mixed Valence States Generated from Dissociation of Polymeric Au (I) Thiolates. Journal of Physical Chemistry C. ,vol. 114, pp. 7727- 7732 ,(2010) , 10.1021/JP9122584
Xun Yuan, Zhentao Luo, Qingbo Zhang, Xinhai Zhang, Yuangang Zheng, Jim Yang Lee, Jianping Xie, Synthesis of highly fluorescent metal (Ag, Au, Pt, and Cu) nanoclusters by electrostatically induced reversible phase transfer. ACS Nano. ,vol. 5, pp. 8800- 8808 ,(2011) , 10.1021/NN202860S
Li Shang, Shaojun Dong, G. Ulrich Nienhaus, Ultra-small fluorescent metal nanoclusters: Synthesis and biological applications Nano Today. ,vol. 6, pp. 401- 418 ,(2011) , 10.1016/J.NANTOD.2011.06.004
Mathias Brust, Merryl Walker, Donald Bethell, David J. Schiffrin, Robin Whyman, Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid-liquid system Journal of The Chemical Society, Chemical Communications. pp. 801- 802 ,(1994) , 10.1039/C39940000801
Prasenjit Maity, Songhai Xie, Miho Yamauchi, Tatsuya Tsukuda, Stabilized gold clusters: from isolation toward controlled synthesis Nanoscale. ,vol. 4, pp. 4027- 4037 ,(2012) , 10.1039/C2NR30900A
M.M. Alvarez, J.T. Khoury, T.G. Schaaff, M. Shafigullin, I. Vezmar, R.L. Whetten, Critical sizes in the growth of Au clusters Chemical Physics Letters. ,vol. 266, pp. 91- 98 ,(1997) , 10.1016/S0009-2614(96)01535-7
Robert L. Donkers, Dongil Lee, Royce W. Murray, Synthesis and Isolation of the Molecule-like Cluster Au38(PhCH2CH2S)24 Langmuir. ,vol. 20, pp. 1945- 1952 ,(2004) , 10.1021/LA035706W
Joseph F. Parker, Christina A. Fields-Zinna, Royce W. Murray, The story of a monodisperse gold nanoparticle: Au25L18. Accounts of Chemical Research. ,vol. 43, pp. 1289- 1296 ,(2010) , 10.1021/AR100048C