Molecular size distributions of dissolved organic matter

作者: Bruce E. Logan , Qing Jiang

DOI: 10.1061/(ASCE)0733-9372(1990)116:6(1046)

关键词:

摘要: Discrete molecular size distributions of dissolved organic matter (DOM) in natural waters and wastewaters are usually determined using an array ultrafiltration membranes stirred cells. However, many researchers neglect membrane rejection, resulting underestimation DOM low weight classes. In this paper, we develop a simple model, based on permeation coefficient, that can be used to improve the accuracy distributions. Since coefficients function material water composition, these must for every sample. The utility model is demonstrated by comparing unadjusted adjusted carbon (DOC) ground municipal wastewaters. For example, when rejection neglected, 41% DOC Biscayne Aquifer has apparent greater than 5,000 amu. Size permeating coefficient however, indicate only 16%

参考文章(19)
Gary L. Amy, Curtis W. Bryant, Mosen Belyani, Molecular Weight Distributions of Soluble Organic Matter in Various Secondary and Tertiary Effluents Water Science and Technology. ,vol. 19, pp. 529- 538 ,(1987) , 10.2166/WST.1987.0232
Gary L. Amy, Michael R. Collins, C. James Kuo, Paul H. King, Comparing Gel Permeation Chromatography and Ultrafiltration for the Molecular Weight Characterization of Aquatic Organic Matter Journal - American Water Works Association. ,vol. 79, pp. 43- 49 ,(1987) , 10.1002/J.1551-8833.1987.TB02782.X
Michael W Chudacek, Anthony G Fane, The dynamics of polarisation in unstirred and stirred ultrafiltration Journal of Membrane Science. ,vol. 21, pp. 145- 160 ,(1984) , 10.1016/S0376-7388(00)81551-3
M. C. Porter, Concentration Polarization with Membrane Ultrafiltration Industrial & Engineering Chemistry Product Research and Development. ,vol. 11, pp. 234- 248 ,(1972) , 10.1021/I360043A002
Eun Namkung, Bruce E. Rittmann, Soluble microbial products (SMP) formation kinetics by biofilms Water Research. ,vol. 20, pp. 795- 806 ,(1986) , 10.1016/0043-1354(86)90106-5
Michael R. Collins, Gary L. Amy, Cornelius. Steelink, Molecular weight distribution, carboxylic acidity, and humic substances content of aquatic organic matter: implications for removal during water treatment. Environmental Science & Technology. ,vol. 20, pp. 1028- 1032 ,(1986) , 10.1021/ES00152A011
J. Knuutinen, L. Virkki, P. Mannila, P. Mikkelson, J. Paasivirta, S. Herve, High-performance liquid chromatographic study of dissolved organic matter in natural waters Water Research. ,vol. 22, pp. 985- 990 ,(1988) , 10.1016/0043-1354(88)90145-5
Cary T. Chiou, Ronald L. Malcolm, Terry I. Brinton, Daniel E. Kile, Water solubility enhancement of some organic pollutants and pesticides by dissolved humic and fulvic acids Environmental Science & Technology. ,vol. 20, pp. 502- 508 ,(1986) , 10.1021/ES00147A010