1,4-Diazo-niabicyclo-[2.2.2]octane diaqua-dichlorido-(oxalato-κO,O')iron(III) chloride.
作者： Ying Cai
DOI: 10.1107/S1600536809025628
关键词:
摘要: In the title compound, (C6H14N2)[Fe(C2O4)Cl2(H2O)2]Cl, all ions are situated on twofold rotational axes. The FeIII ion is coordinated by two O atoms from a chelating oxalate ligand, water molecules and chloride anions in distorted octahedral geometry. Intermolecular N—H⋯O, O—H⋯O O—H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates crystal packing.
sci-hub.st 参考文章(7)
Yunlong Fu, Yunling Liu, Zhan Shi, Baozong Li, Wenqin Pang, Hydrothermal Synthesis and Characterization of Four Oxalatotitanates with Ti4O4(C2O4)8 Tetramers as Basic Building Blocks Journal of Solid State Chemistry. ,vol. 163, pp. 427- 435 ,(2002) , 10.1006/JSSC.2001.9422
Ming-Yuan Lee, Sue-Lein Wang, Syntheses and Characterizations of Four Organically Templated One-Dimensional Molybdenum Compounds including the First Inorganic−Organic Mixed-Anion Structures in the Mo/X/O (X = As, P) System Chemistry of Materials. ,vol. 11, pp. 3588- 3594 ,(1999) , 10.1021/CM990370Q
Jun Zhao, Li Xu, Protonated N-heterocycle-templated supramolecular frameworks built of triangular molybdenum(IV) clusters Inorganica Chimica Acta. ,vol. 361, pp. 2385- 2395 ,(2008) , 10.1016/J.ICA.2007.12.013
Tony D. Keene, Michael B. Hursthouse, Daniel J. Price, 1,4-Diazoniabicyclo[2.2.2]octane aquabis(oxalato-κ2O,O′)copper(II) dihydrate Acta Crystallographica Section E-structure Reports Online. ,vol. 60, ,(2004) , 10.1107/S1600536804005033
H. D. Flack, On enantiomorph‐polarity estimation Acta Crystallographica Section A. ,vol. 39, pp. 876- 881 ,(1983) , 10.1107/S0108767383001762
George M. Sheldrick, A short history of SHELX Acta Crystallographica Section A. ,vol. 64, pp. 112- 122 ,(2008) , 10.1107/S0108767307043930
Sukhendu Mandal, Srinivasan Natarajan, Inorganic–Organic Hybrid Structures: Open‐Framework Iron Phosphite–Oxalates of Varying Dimensionality Chemistry: A European Journal. ,vol. 13, pp. 968- 977 ,(2007) , 10.1002/CHEM.200601026