X-Ray Structural Analysis of Diiron Complex with Tris(4-methoxyphenyl)phosphine
作者： Yu Tan , Qing Zou , Xu-feng Liu
DOI: 10.1080/15421406.2015.1036511
关键词:
摘要: The title complex was synthesized by the reaction of (μ-SCH2CH2CH2S-μ)Fe2(CO)6 with tris(4-methoxyphenyl)phosphine in presence decarbonylating agent Me3NO·2H2O CH2Cl2/MeCN solutions. molecular structure analyzed X-ray diffraction analysis. contains a butterfly diiron dithiolate cluster five terminal carbonyls and tris(4-methoxyphenyl)phosphine. phosphorus atom resides an apical position square-pyramidal geometry neighboring Fe2 atom. Intermolecular C‒H…O hydrogen bonds between phenyl carbonyl groups stabilize solid state crystal packing.
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