Unexpected oxidation of a diphosphine by bis(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2].
作者： David J. Harding , Phimphaka Harding , Theerapol Thurakitseree , Harry Adams
DOI: 10.1107/S010827010700933X
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摘要: The reaction of bis(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)(2)], with bis(diphenylphosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis(1,3-diphenylpropane-1,3-dionato-kappa(2)O,O')cobalt(II)]-mu-ethylenebis(diphenylphosphine oxide)-kappa(2)O:O'], trans-[Co(C(15)H(11)O(2))(2)(C(26)H(24)O(2)P(2))](n), as a result oxidation diphosphine. Co atom is octahedral, CoO(6) sphere, and chelating dbm ligands adopt trans configuration. also lies on centre inversion, further symmetry bisecting bridging ethylenebis(diphenylphosphine oxide) ligand.
sci-hub.se 参考文章(9)
Ferman A. Chavez, Jorge A. Briones, Marilyn M. Olmstead, Pradip K. Mascharak, Syntheses and Stuctures of Alkyl Peroxo Adducts of β-Diketonate Cobalt(III) Complexes and Their Role in Oxidation of Hydrocarbons and Olefin Epoxidation Inorganic Chemistry. ,vol. 38, pp. 1603- 1608 ,(1999) , 10.1021/IC980970B
Davide Barreca, Cristian Massignan, Sergio Daolio, Monica Fabrizio, Clara Piccirillo, Lidia Armelao, Eugenio Tondello, Composition and Microstructure of Cobalt Oxide Thin Films Obtained from a Novel Cobalt(II) Precursor by Chemical Vapor Deposition Chemistry of Materials. ,vol. 13, pp. 588- 593 ,(2001) , 10.1021/CM001041X
Long-Cheng Wang, Hye-Young Jang, Yeonsuk Roh, Vincent Lynch, Arthur J. Schultz, Xiaoping Wang, Michael J. Krische, Diastereoselective cycloreductions and cycloadditions catalyzed by Co(dpm)(2)-silane (dpm = 2,2,6,6-tetramethylheptane-3,5-dionate): mechanism and partitioning of hydrometallative versus anion radical pathways. Journal of the American Chemical Society. ,vol. 124, pp. 9448- 9453 ,(2002) , 10.1021/JA020223K
Shigeru Isayama, An efficient method for the direct peroxygenation of various olefinic compounds with molecular oxygen and triethylsilane catalyzed by a cobalt(II) complex Bulletin of the Chemical Society of Japan. ,vol. 63, pp. 1305- 1310 ,(1990) , 10.1246/BCSJ.63.1305
Sergej Pasko, Liliane G. Hubert-Pfalzgraf, Adulfas Abrutis, Jacqueline Vaissermann, Synthesis and molecular structures of cobalt(II) β-diketonate complexes as new MOCVD precursors for cobalt oxide films Polyhedron. ,vol. 23, pp. 735- 741 ,(2004) , 10.1016/J.POLY.2003.11.044
O.V. Koreneva, G.V. Romanenko, Yu.G. Shvedenkov, V.N. Ikorskii, V.I. Ovcharenko, Molecular magnets based on M(hfac)2 and spin-labeled nitrile Polyhedron. ,vol. 22, pp. 2487- 2497 ,(2003) , 10.1016/S0277-5387(03)00229-8
Norio Ishii, Takayuki Ishida, Takashi Nogami, Polymorphic alternating HNN-cobalt(II) chains both behaving as single-chain magnets (HNN = 4,4,5,5-tetramethylimidazolin-1-oxyl 3-oxide). Inorganic Chemistry. ,vol. 45, pp. 3837- 3839 ,(2006) , 10.1021/IC052119K
Christer B. Aakeröy, Nate Schultheiss, John Desper, Directed Supramolecular Assembly of Infinite 1-D M(II)-Containing Chains (M = Cu, Co, Ni) Using Structurally Bifunctional Ligands Inorganic Chemistry. ,vol. 44, pp. 4983- 4991 ,(2005) , 10.1021/IC048405Y
J. P. Fackler, F. A. Cotton, ELECTRONIC STRUCTURE AND MOLECULAR ASSOCIATION OF SOME BIS-(β-DIKETONE)-NICKEL(II) COMPLEXES Journal of the American Chemical Society. ,vol. 82, pp. 5005- 5006 ,(1960) , 10.1021/JA01503A065