Predictive radiation field modeling for fluidized bed photocatalytic reactors

作者: Gustavo E. Imoberdorf , Fariborz Taghipour , Mehrdad Keshmiri , Madjid Mohseni

DOI: 10.1016/J.CES.2008.05.022

关键词:

摘要: Abstract A predictive model of the radiation distribution for fluidized bed photocatalytic reactors was proposed and solved by means Monte Carlo approach coupled with ray tracing technique. This considers interaction between TiO 2 -coated spheres photons, taking into account shadowing effect beads, reflection on surface spheres, absorption in films. is completely does not use any adjustable parameter. Modeling results indicate a strong influence expansion distribution, beads being main cause this dependence. Increasing improves uniformity reactor. Nevertheless, an excessively expanded would reduce efficiency reactor because transmittance increases fraction photons leave without absorbed spheres. The evaluated laboratory-scale that designed built elimination organic pollutants from water streams. glass diameter 1.18 mm were used as photocatalyst. validated comparing predicted values effective experimental measured under different expansions. performance also assessed experimentally, showing good degradation formic acid compound.

参考文章(33)
Quan Yang, Pei Ling Ang, Madhumita B. Ray, Simo O. Pehkonen, Light distribution field in catalyst suspensions within an annular photoreactor Chemical Engineering Science. ,vol. 60, pp. 5255- 5268 ,(2005) , 10.1016/J.CES.2005.02.067
Hidehiro Kumazawa, Makoto Inoue, Tomomichi Kasuya, Photocatalytic Degradation of Volatile and Nonvolatile Organic Compounds on Titanium Dioxide Particles Using Fluidized Beds Industrial & Engineering Chemistry Research. ,vol. 42, pp. 3237- 3244 ,(2003) , 10.1021/IE020723M
Andreas Haarstrick, Oemer M. Kut, Elmar Heinzle, TiO2-Assisted Degradation of Environmentally Relevant Organic Compounds in Wastewater Using a Novel Fluidized Bed Photoreactor Environmental Science & Technology. ,vol. 30, pp. 817- 824 ,(1996) , 10.1021/ES9502278
Mehrdad Keshmiri, Madjid Mohseni, Tom Troczynski, Development of novel TiO2 sol–gel-derived composite and its photocatalytic activities for trichloroethylene oxidation Applied Catalysis B-environmental. ,vol. 53, pp. 209- 219 ,(2004) , 10.1016/J.APCATB.2004.05.016
A. Haider, O. Levenspiel, Drag coefficient and terminal velocity of spherical and nonspherical particles Powder Technology. ,vol. 58, pp. 63- 70 ,(1989) , 10.1016/0032-5910(89)80008-7
Matteo Pasquali, Francesco Santarelli, John F. Porter, Po-Lock Yue, Radiative transfer in photocatalytic systems Aiche Journal. ,vol. 42, pp. 532- 537 ,(1996) , 10.1002/AIC.690420222
Alberto E. Cassano, Carlos A. Martin, Rodolfo J. Brandi, Orlando M. Alfano, Photoreactor Analysis and Design: Fundamentals and Applications Industrial & Engineering Chemistry Research. ,vol. 34, pp. 2155- 2201 ,(1995) , 10.1021/IE00046A001
M.G Chiovetta, R.L Romero, A.E Cassano, Modeling of a fluidized-bed photocatalytic reactor for water pollution abatement Chemical Engineering Science. ,vol. 56, pp. 1631- 1638 ,(2001) , 10.1016/S0009-2509(00)00391-2
Tak Hyoung Lim, Sang Done Kim, Photocatalytic degradation of trichloroethylene (TCE) over TiO2/silica gel in a circulating fluidized bed (CFB) photoreactor Chemical Engineering and Processing. ,vol. 44, pp. 327- 334 ,(2005) , 10.1016/J.CEP.2004.02.027
Lynette A. Dibble, Gregory B. Raupp, Fluidized-bed photocatalytic oxidation of trichloroethylene in contaminated air streams Environmental Science & Technology. ,vol. 26, pp. 492- 495 ,(1992) , 10.1021/ES00027A006