Prediction of viscosity of binary solvent mixtures at various temperatures

作者: A. Jouyban , S.H. Maljaei , Sh. Soltanpour , M.A.A. Fakhree

DOI: 10.1016/J.MOLLIQ.2011.06.002

关键词:

摘要: Abstract Combined forms of the Jouyban–Acree model and calculated Abraham solute parameters as descriptors for solvents were used predicting viscosity binary solvent mixtures at various temperatures. The proposed models tested on a large number experimental data miscible mixtures. mean relative deviations (MRDs) between computed are an accuracy criterion. overall MRD investigated is 17%. With including mono-solvents, prediction capability improved 7%. A reduced form could be to compute mono-solvents temperatures with 27%.

参考文章(73)
William E. Acree, Mathematical representation of thermodynamic properties Thermochimica Acta. ,vol. 198, pp. 71- 79 ,(1992) , 10.1016/0040-6031(92)85059-5
S. Singh, S. Parveen, D. Shukla, M. Gupta, J.P. Shukla, Volumetric, Optical, Acoustical and Viscometric Study of Molecular Association in Binary Mixtures of Butylamine with 1-Butanol and Tert-Butanol Acta Physica Polonica A. ,vol. 111, pp. 847- 858 ,(2007) , 10.12693/APHYSPOLA.111.847
Luis H. Blanco, Eliseo Amado Gonzalez, Conductance of Asymmetric Iodides of Butyl-Triethyl-Ammonium in Toluene-Acetonitrile Mixtures at 25°C Physics and Chemistry of Liquids. ,vol. 30, pp. 213- 226 ,(1995) , 10.1080/00319109508030668
B. Giner, H. Artigas, M. Haro, C. Lafuente, M.C. López, Viscosities of binary mixtures of 1,3-dioxolane or 1,4-dioxane with isomeric chlorobutanes Journal of Molecular Liquids. ,vol. 129, pp. 176- 180 ,(2006) , 10.1016/J.MOLLIQ.2006.03.048
S. L. Oswal, R. P. Phalak, Viscosities of nonelectrolyte liquid mixtures. I : Binary mixtures containing p-dioxane International Journal of Thermophysics. ,vol. 13, pp. 251- 267 ,(1992) , 10.1007/BF00504435