The kinetics of oxidation of uranium powder and foil in carbon dioxide in the range 375 to 602°C

作者: R.M. Alire , A.W. Czanderna , R.L. Wittaker

DOI: 10.1016/0022-3115(77)90140-4

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摘要: Abstract The kinetics of oxidation uranium powder and foil with CO2 in the pressure range 24–117 torr temperature 390–602°C were investigated. results adequately represented by a model that included nucleation radial growth disks followed diffusion across product layer. activation energies ΔE's for 32 ± 2 kcal/mol coupons, 34 powder. For 26 coupons 12 1 24 22

参考文章(17)
E. Robens, The Effect of Thermal Gas Motion on Microbalance Measurements Vacuum Microbalance Techniques. pp. 73- 95 ,(1971) , 10.1007/978-1-4757-0133-3_6
J.J. Stobbs, On cracking and carbon pickup in the oxide formed on uranium in carbon dioxide at 650°C Journal of The Less Common Metals. ,vol. 10, pp. 362- 365 ,(1966) , 10.1016/0022-5088(66)90137-8
J. Païdassi, M.L. Pointud, R. Caillat, R. Darras, Contribution a l'etude de l'oxydation de l'uranium dans l'anhydride carbonique aux temperatures elevees Journal of Nuclear Materials. ,vol. 3, pp. 162- 174 ,(1961) , 10.1016/0022-3115(61)90004-6
W. P. Ellis, B. D. Campbell, Secondary‐Electron Energy Distribution Studies of UO2 Surfaces Journal of Applied Physics. ,vol. 41, pp. 1858- 1861 ,(1970) , 10.1063/1.1659117
R. M. Alire, B. A. Mueller, Charles L. Peterson, John R. Mosley, Reaction Kinetics of Uranium and Deuterium The Journal of Chemical Physics. ,vol. 52, pp. 37- 46 ,(1970) , 10.1063/1.1672694
L. Baker, J.D. Bingle, The kinetics of oxidation of uranium between 300 and 625° C Journal of Nuclear Materials. ,vol. 20, pp. 11- 21 ,(1966) , 10.1016/0022-3115(66)90017-1
R.J. Pearce, I. Whittle, D.A. Hilton, The oxidation of uranium in carbon dioxide and carbon monoxide (A review) Journal of Nuclear Materials. ,vol. 33, pp. 1- 16 ,(1969) , 10.1016/0022-3115(69)90002-6
A. W. Czanderna, J. M. Honig, Sensitive Quartz Beam Microbalance Analytical Chemistry. ,vol. 29, pp. 1206- 1210 ,(1957) , 10.1021/AC60128A029
R. M. Alire, J. H. McCrary, Reaction Kinetics of Powdered Uranium and Deuteroammonia Journal of Chemical Physics. ,vol. 45, pp. 3958- 3965 ,(1966) , 10.1063/1.1727445
J.J. Stobbs, I. Whittle, The influence of impurities on the oxidation of uranium in carbon dioxide between 450° and 650° C Journal of Nuclear Materials. ,vol. 19, pp. 160- 168 ,(1966) , 10.1016/0022-3115(66)90106-1