Thermolysis, photolysis, and oxidation of an overcrowded 1,3,2‐dithiastannetane derivative
作者： Norihiro Tokitoh , Verena Stresing , Yasusuke Matsuhashi , Renji Okazaki
DOI: 10.1002/HC.520060209
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摘要: Reactions of a sterically crowded 1,3,2-dithiastannetane derivative bearing 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (=Tbt) and 2,4,6-triisopropylphenyl (=Tip) groups on the tin atom are described. Both thermolysis photolysis [Tbt(Tip)SnS2CPh2] resulted in formation products derived from corresponding stannanethione [Tbt(Tip)Sn=S], while oxidation reaction by m-chloroperbenzoic acid gave novel tincontaining heterocyclic system, an 1,2,4,5-oxadithiastannolane derivative.
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