A Unified Strategy to ent-Kauranoid Natural Products: Total Syntheses of (−)-Trichorabdal A and (−)-Longikaurin E

作者: John T. S. Yeoman , Victor W. Mak , Sarah E. Reisman

DOI: 10.1021/JA406599A

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摘要: The first total syntheses of (−)-trichorabdal A and (−)-longikaurin E are reported. A unified synthetic strategy is employed that relies on a Pd-mediated oxidative cyclization of a silyl …

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