Chiroptical properties of the diazirine chromophore
作者： G. V. Shustov , S. V. Varlamov , A. Rauk , R. G. Kostyanovskii
DOI: 10.1021/JA00165A024
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摘要: Measurement of the CD spectra (αS)-3-sec-butyldiazirine, (5S)-5-methyl-1,2-diazaspiro [2.5] oct-1-ene, (4R,7R)-4-isopropyl-7-methyl-1,2-diazaspiro 3-azi-5α-cholestane, and 3-azi-5α-androstan-17β-yl benzoate computations on gauche-3-ethyldiazirine suggest that Cotton effect long wavelength (350-370 nm) absorption obeys an octant rule
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