HYDROGEN PERMEABILITY OF PALLADIUM MEMBRANE FOR STEAM-REFORMING OF BIO-ETHANOL USING THE MEMBRANE REACTOR
作者： KOUJI KINOUCHI , MASAHIRO KATOH , TOSHIHIDE HORIKAWA , TAKUSHI YOSHIKAWA , MAMORU WADA
DOI: 10.1142/S2010194512002851
关键词:
摘要: A Palladium membrane was prepared by electro-less plating method on porous stainless steel. The catalytic hydrogen production steam-reforming of biomass-derived ethanol (bio-ethanol) using a Pd analyzed comparing it with those for the reaction reagent (the reference sample). And permeability palladium investigated same (H2/He selectivity = 249, at ΔP 0.10 MPa, 873 K). As result, bio-ethanol, deposited carbon had negative influence hydrogen-permeability and purity. sulfur content in bio-ethanol may have promoted deposition. By membrane, confirmed that H2 yield (%) increased. It can be attributed methane converted from produced more steam reforming, due to situ removal location.
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sci-hub.se 参考文章(15)
L BARELLI, G BIDINI, A CORRADETTI, U DESIDERI, Study of the carbonation-calcination reaction applied to the hydrogen production from syngas Energy. ,vol. 32, pp. 697- 710 ,(2007) , 10.1016/J.ENERGY.2006.04.016
Masahiro Katoh, Koichi Chohama, Etsumi Sakata, Toshihide Horikawa, Tahei Tomida, XPS Study of the Influence of CO2 on the H2 Flux through a Composite Membrane Made of Palladium and Porous Stainless Steel Journal of Chemical Engineering of Japan. ,vol. 43, pp. 745- 750 ,(2010) , 10.1252/JCEJ.09WE213
Abayomi J. Akande, Raphael O. Idem, Ajay K. Dalai, Synthesis, characterization and performance evaluation of Ni/Al2O3 catalysts for reforming of crude ethanol for hydrogen production Applied Catalysis A-general. ,vol. 287, pp. 159- 175 ,(2005) , 10.1016/J.APCATA.2005.03.046
MASAHIRO KATOH, KATSUNORI NISHIHARA, KOJI KINOUCHI, KOICHI CHOHAMA, TOSHIHIDE HORIKAWA, TAHEI TOMIDA, KEN-ICHIRO SOTOWA, THE EFFECT OF CARBON MONOXIDE ON THE HYDROGEN PERMEABILITY OF A PALLADIUM MEMBRANE International Journal of Modern Physics B. ,vol. 24, pp. 2833- 2837 ,(2010) , 10.1142/S0217979210065714
José Comas, Fernando Mariño, Miguel Laborde, Norma Amadeo, Bio-ethanol steam reforming on Ni/Al2O3 catalyst Chemical Engineering Journal. ,vol. 98, pp. 61- 68 ,(2004) , 10.1016/S1385-8947(03)00186-4
Masahiro Katoh, Tatsuya Yamazaki, Naoko Kikuchi, Yoshie Okada, Takushi Yoshikawa, Mamoru Wada, Conversion of Bio-ethanol into Hydrocarbons over HZSM-5 Catalyst Kagaku Kogaku Ronbunshu. ,vol. 34, pp. 396- 401 ,(2008) , 10.1252/KAKORONBUNSHU.34.396
Peter P. Mardilovich, Ying She, Yi Hua Ma, Min-Hon Rei, Defect‐free palladium membranes on porous stainless‐steel support Aiche Journal. ,vol. 44, pp. 310- 322 ,(1998) , 10.1002/AIC.690440209
F. Haga, T. Nakajima, K. Yamashita, S. Mishima, Effect of crystallite size on the catalysis of alumina-supported cobalt catalyst for steam reforming of ethanol Reaction Kinetics and Catalysis Letters. ,vol. 63, pp. 253- 259 ,(1998) , 10.1007/BF02475396
M Benito, JL Sanz, R Isabel, R Padilla, R Arjona, L Daza, None, Bio-ethanol steam reforming: Insights on the mechanism for hydrogen production Journal of Power Sources. ,vol. 151, pp. 11- 17 ,(2005) , 10.1016/J.JPOWSOUR.2005.02.046
Meng Ni, Dennis Y.C. Leung, Michael K.H. Leung, A review on reforming bio-ethanol for hydrogen production International Journal of Hydrogen Energy. ,vol. 32, pp. 3238- 3247 ,(2007) , 10.1016/J.IJHYDENE.2007.04.038