Enthalpies of formation of some phases present in the Y-Ba-Cu-O system by solution calorimetry

作者: Zhang Hengzhong , Fang Zheng , Zhang Pingmin , Chen Xinmin

DOI: 10.1007/BF00973207

关键词:

摘要: Enthalpies of some the phases in Y−Ba−Cu−O system were determined by solution calorimetry using a Calvet microcalorimeter. The standard enthalpies formation for found to be YBa2Cu3O6.60, −2627.9; YBa2Cu3O6.77, −2641.8; YBa2Cu3O6.90, −2652.0; YBa2Cu3O6.99, −2659.3; Y2Cu2O5, −2198.6; Y2BaCuO5, −2656.4; BaCuO2.33, −788.6; and BaCuO2.42, −796.2 kJ-mol−1.

参考文章(12)
G.K. Moiseev, N.A. Vatolin, S.I. Zaizeva, N.I. Ilyinych, D.S. Tsagareishvili, G.G. Gvelesiani, I.B. Baratashvili, J. Šesták, Calculation of thermodynamic properties of the phases in the Y-Ba-Cu-O system Thermochimica Acta. ,vol. 198, pp. 267- 278 ,(1992) , 10.1016/0040-6031(92)85083-8
K. Conder, S. Rusiecki, E. Kaldis, High accuracy volumetric determination of oxygen in YBaCuO superconductors: YBa2Cu3O6.5+x Materials Research Bulletin. ,vol. 24, pp. 581- 587 ,(1989) , 10.1016/0025-5408(89)90105-0
R. Pankajavalli, O. M. Sreedharan, Thermodynamic stability of Y2Cu2O5 by e.m.f. method Journal of Materials Science Letters. ,vol. 7, pp. 714- 716 ,(1988) , 10.1007/BF00722077
Fernando H. Garzon, Ian D. Raistrick, D.S. Ginley, John W. Halloran, Thermodynamic instability of the YBa2Cu3O7−x phase at the 1/2/3 composition Journal of Materials Research. ,vol. 6, pp. 885- 887 ,(1991) , 10.1557/JMR.1991.0885
G.F. Voronin, S.A. Degterov, Thermodynamics of superconducting phases in the Y-Ba-Cu-O system Physica C: Superconductivity. ,vol. 176, pp. 387- 408 ,(1991) , 10.1016/0921-4534(91)90042-W
P.K. Gallagher, H.M. O'Bryan, G.S. Grader, Reduction of Ba2YCu3O7 and Y2Cu2O5 by H2 Thermochimica Acta. ,vol. 137, pp. 373- 381 ,(1989) , 10.1016/0040-6031(89)87229-6
A.F. Maiorova, S.N. Mudretsova, S.F. Pashin, M.A. Bykov, Thermochemical characteristics of BaCuO2 Thermochimica Acta. ,vol. 197, pp. 219- 224 ,(1992) , 10.1016/0040-6031(92)87053-D
U. Wiesner, G. Krabbes, M. Ritschel, Stability fields in the system YCuO and thermochemical data of Y2Cu2O5 and YCuO2 Materials Research Bulletin. ,vol. 24, pp. 1261- 1266 ,(1989) , 10.1016/0025-5408(89)90201-8
Zhigang Zhou, Alexandra Navrotsky, Thermochemistry of the Y2O3–BaO–Cu–O system Journal of Materials Research. ,vol. 7, pp. 2920- 2935 ,(1992) , 10.1557/JMR.1992.2920
Zhanguo Fan, Chunlin Ji, Zhongxian Zhao, Standard gibbs free energy of formation of superconducting YBa2Cu3Ox and related compounds in the Y2O3BaOCuO system Journal of The Less Common Metals. ,vol. 161, pp. 49- 59 ,(1990) , 10.1016/0022-5088(90)90313-9