Evaluation of batch and column techniques to measure weathering rates in soils.

作者: J.J.M. van Grinsven , W.H. van Riemsdijk

DOI: 10.1016/0016-7061(92)90074-H

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摘要: Abstract Six batch and column techniques were evaluated with respect to their potential measure realistic weathering rates in soil. Soil samples taken from a C-horizon of Dystrochrept. Rates observed the laboratory one three orders magnitude higher than those inferred field studies. Batch that involve stirring or shaking, generally gave highest rates, probably due abrasion mineral particles. Column are be preferred, but classical leaching experiment chemical conditions pore water may vary considerably within over duration experiment. To reduce variation titration experiment, new technique was used, which influx protons automatically adjusted proportionally overall buffering rate. Results show dissolution for base cations aluminum strongly decrease extent reaction. Experimental evidence found an increase percolation rate will Although underlying mechanism relationship between is not yet clear, this explain important part discrepancy studies field.

参考文章(25)
Werner Stumm, Gerhard Furrer, Erich Wieland, Bettina Zinder, The Effects of Complex-Forming Ligands on the Dissolution of Oxides and Aluminosilicates Springer Netherlands. pp. 55- 74 ,(1985) , 10.1007/978-94-009-5333-8_4
The chemistry of weathering D. Reidel Pub. Co. , Sold and distributed in the U.S.A. and Canada by Kluwer Academic Publishers. ,(1985) , 10.1007/978-94-009-5333-8
Carl W. Correns, Wolf von Engelhardt, Neue Untersuchungen über die Verwitterung des Kalifeldspates Naturwissenschaften. ,vol. 26, pp. 137- 138 ,(1938) , 10.1007/BF01772798
George R. Holdren, Robert A. Berner, Mechanism of feldspar weathering—I. Experimental studies Geochimica et Cosmochimica Acta. ,vol. 43, pp. 1161- 1171 ,(1979) , 10.1016/0016-7037(79)90109-1
M. J. WILSON, CHEMICAL WEATHERING OF SOME PRIMARY ROCK-FORMING MINERALS Soil Science. ,vol. 119, pp. 349- 355 ,(1975) , 10.1097/00010694-197505000-00004
R. A. Berner, Rate control of mineral dissolution under Earth surface conditions American Journal of Science. ,vol. 278, pp. 1235- 1252 ,(1978) , 10.2475/AJS.278.9.1235
Eurybiades Busenberg, Charles V Clemency, The dissolution kinetics of feldspars at 25°C and 1 atm CO2 partial pressure Geochimica et Cosmochimica Acta. ,vol. 40, pp. 41- 49 ,(1976) , 10.1016/0016-7037(76)90192-7
George R. Holdren, Patricia M. Speyer, Reaction rate-surface area relationships during the early stages of weathering. II. Data on eight additional feldspars Geochimica et Cosmochimica Acta. ,vol. 51, pp. 2311- 2318 ,(1987) , 10.1016/0016-7037(87)90284-5
George R. Holdren, Patricia M. Speyer, Reaction rate-surface area relationships during the early stages of weathering—I. Initial observations Geochimica et Cosmochimica Acta. ,vol. 49, pp. 675- 681 ,(1985) , 10.1016/0016-7037(85)90162-0