Radioisotopic study of (Co)Mo/Al2O3 sulfide catalysts for HDS: Part III. Poisoning by N-containing compounds
作者： V.M Kogan , R.G Gaziev , S.W Lee , N.N Rozhdestvenskaya
DOI: 10.1016/S0926-860X(03)00312-0
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摘要: By using radioisotopic testing technique a poisoning effect of N-containing compounds on sulfided-( 35 S) (Co)Mo catalysts in the reaction thiophene hydrodesulfurization (HDS) has been studied. In course experiments number, distribution and reactivity surface SH groups various types related functioning vacancies as well catalytic activity poisoned non-poisoned Mo CoMo have measured. It shown that desulfurization (DS) hydrogenation (HYD) reactions mostly proceed same sites. These sites are attributed “rapid” belong to Mo. The results compared with literature data HDS dibezothiophene (DBT) its methyl derivatives. comparison 4-methyl- 4,6-dimethyldibenzothiophenes CoMoS demonstrate stronger resistance HYD than DS ones. HDS, opposite trend. suggested alkyl derivatives DBT all should while DBT—on Co products take place A method evaluate efficiency (Co)MoS for crudes developed. © 2003 Elsevier Science B.V. All rights reserved.
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sci-hub.se 参考文章(58)
Line S. Byskov, Jens K. Nørskov, Bjerne S. Clausen, Henrik Topsøe, Edge termination of MoS2 and CoMoS catalyst particles Catalysis Letters. ,vol. 64, pp. 95- 99 ,(2000) , 10.1023/A:1019063709813
F. Pedraza, S. Fuentes, M. Vrinat, M. Lacroix, Deactivation of MoS2 catalysts during the HDS of thiophene Catalysis Letters. ,vol. 62, pp. 121- 126 ,(1999) , 10.1023/A:1019055223984
V LAVOPA, Poisoning of thiophene hydrodesulfurization by nitrogen compounds Journal of Catalysis. ,vol. 110, pp. 375- 387 ,(1988) , 10.1016/0021-9517(88)90328-4
Mária Dobrovolszky, Károly Matusek, Zoltán Paál, Pál Tétényi, Conversion of thiophene on molybdena–alumina catalysts containing Group 8–10 metals: effect of H2S uptake Journal of the Chemical Society, Faraday Transactions. ,vol. 89, pp. 3137- 3142 ,(1993) , 10.1039/FT9938903137
F.E. Massoth, T. Koltai, P. Tétényi, Theoretical Analysis of Sulfur Exchange Experiments Journal of Catalysis. ,vol. 203, pp. 33- 40 ,(2001) , 10.1006/JCAT.2001.3314
R. RAMACHANDRAN, F.E. MASSOTH, THE EFFECTS OF PYRIDINE AND COKE POISONING ON BENZOTHIOPHENE HYDRODESULFURIZATION OVER CoMo/AI2O3 CATALYST† Chemical Engineering Communications. ,vol. 18, pp. 239- 254 ,(1982) , 10.1080/00986448208939969
V.M Kogan, N.N Rozhdestvenskaya, I.K Korshevets, Radioisotopic study of CoMo/Al2O3 sulfide catalysts for HDS. Part I: Active site monitoring Applied Catalysis A-general. ,vol. 234, pp. 207- 219 ,(2002) , 10.1016/S0926-860X(02)00225-9
Chan Kwak, Jung Joon Lee, Jun Sang Bae, Sang Heup Moon, Poisoning effect of nitrogen compounds on the performance of CoMoS/Al2O3 catalyst in the hydrodesulfurization of dibenzothiophene, 4-methyldibenzothiophene, and 4,6-dimethyldibenzothiophene Applied Catalysis B-environmental. ,vol. 35, pp. 59- 68 ,(2001) , 10.1016/S0926-3373(01)00233-8
Hannes Schweiger, Pascal Raybaud, Georg Kresse, Hervé Toulhoat, Shape and Edge Sites Modifications of MoS2 Catalytic Nanoparticles Induced by Working Conditions: A Theoretical Study Journal of Catalysis. ,vol. 207, pp. 76- 87 ,(2002) , 10.1006/JCAT.2002.3508
Toshiaki Kabe, Weihua Qian, Atsushi Ishihara, Study of hydrodesulfurization by the use of sulfur-35-labeled dibenzothiophene. 2. Behavior of sulfur in hydrodesulfurization, hydrodeoxygenation, and hydrodenitrogenation on a sulfided molybdenum/alumina catalyst The Journal of Physical Chemistry. ,vol. 98, pp. 912- 916 ,(1994) , 10.1021/J100054A028