Redox-Induced Aromatic C–H Bond Functionalization in Metal Complex Catalysis from the Electrochemical Point of View
作者： Yulia Budnikova , Yulia Dudkina , Mikhail Khrizanforov
DOI: 10.3390/INORGANICS5040070
关键词:
摘要: This review generalizes and specifies the oxidizing ability of a number oxidants used in palladium (Pd)-catalyzed aromatic C–H functionalizations. The redox potentials have been analyzed as measure oxidant strength applied to reasoning efficiency known reactions where catalytic cycles include cyclometalated complexes (and other organopalladium key intermediates).
mdpi.com
core.ac.uk
sci-hub.se 参考文章(97)
Chaojie Song, Jiujun Zhang, Electrocatalytic Oxygen Reduction Reaction Springer, London. pp. 89- 134 ,(2008) , 10.1007/978-1-84800-936-3_2
S Wacławek, K Grübel, M Černík, None, Simple spectrophotometric determination of monopersulfate. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 149, pp. 928- 933 ,(2015) , 10.1016/J.SAA.2015.05.029
Tatyana Gryaznova, Yulia Dudkina, Mikhail Khrizanforov, Oleg Sinyashin, Olga Kataeva, Yulia Budnikova, Electrochemical properties of diphosphonate-bridged palladacycles and their reactivity in arene phosphonation Journal of Solid State Electrochemistry. ,vol. 19, pp. 2665- 2672 ,(2015) , 10.1007/S10008-015-2875-Y
MN Khrizanforov, DM Arkhipova, RP Shekurov, TP Gerasimova, VV Ermolaev, DR Islamov, VA Miluykov, ON Kataeva, VV Khrizanforova, OG Sinyashin, Yu H Budnikova, None, Novel paste electrodes based on phosphonium salt room temperature ionic liquids for studying the redox properties of insoluble compounds Journal of Solid State Electrochemistry. ,vol. 19, pp. 2883- 2890 ,(2015) , 10.1007/S10008-015-2901-0
Duo Zhang, Xiuling Cui, Fangfang Yang, Qianqian Zhang, Yu Zhu, Yangjie Wu, Palladium-catalyzed direct ortho C–O bond construction of azoxybenzenes with carboxylic acids and alcohols Organic chemistry frontiers. ,vol. 2, pp. 951- 955 ,(2015) , 10.1039/C5QO00120J
Scott D. Rychnovsky, Rajappa Vaidyanathan, Thomas Beauchamp, Rong Lin, Patrick J. Farmer, AM1-SM2 Calculations Model the Redox Potential of Nitroxyl Radicals Such as TEMPO. Journal of Organic Chemistry. ,vol. 64, pp. 6745- 6749 ,(1999) , 10.1021/JO990636C
Pedro Villuendas, Elena Serrano, Esteban P Urriolabeitia, None, Pd-catalysed ortho-alkoxylation of benzamides N-protected with an iminophosphorane functionality New Journal of Chemistry. ,vol. 39, pp. 3077- 3083 ,(2015) , 10.1039/C5NJ00189G
Peter Wardman, Reduction Potentials of One‐Electron Couples Involving Free Radicals in Aqueous Solution Journal of Physical and Chemical Reference Data. ,vol. 18, pp. 1637- 1755 ,(1989) , 10.1063/1.555843
B.V. Subba Reddy, N. Umadevi, G. Narasimhulu, J.S. Yadav, Oxidative C–H functionalization: a novel strategy for the acetoxylation/alkoxylation of arenes tethered to 3,4-dihydroisoquinolines Tetrahedron Letters. ,vol. 53, pp. 6091- 6094 ,(2012) , 10.1016/J.TETLET.2012.08.124
Paul L. Alsters, Pim F. Engel, Marinus P. Hogerheide, Marc Copijn, Anthony L. Spek, Gerard van Koten, Rigid five- and six-membered C,N,N' bound aryl, benzyl, and alkyl organopalladium complexes : sp2 vs. sp3 C-H activation during cyclopalladation and palladium(IV) intermediates in oxidative addition reactions with dihalogens and alkyl halides Organometallics. ,vol. 12, pp. 1831- 1844 ,(1993) , 10.1021/OM00029A045