Transition metal borylene complexes: boron analogues of classical organometallic systems

作者: Dragoslav Vidovic , Glesni A. Pierce , Simon Aldridge

DOI: 10.1039/B816042B

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摘要: In the ten years since first examples of terminal borylene complexes were reported, rapid advances in chemistry this ligand class have been made, and parallels emerged with classical organometallic systems (such as carbenes, vinylidenes even CO) well other subvalent main group systems. This article reviews key developments synthetic, structural reaction chemistry, particular attention focusing on recent discoveries field.

参考文章(140)
Simon Aldridge, Deborah L. Coombs, Transition metal boryl and borylene complexes: substitution and abstraction chemistry Coordination Chemistry Reviews. ,vol. 248, pp. 535- 559 ,(2004) , 10.1016/J.CCR.2003.12.003
P. L. Timms, Boron-fluorine chemistry. II. Reaction of boron monofluoride with acetylenes Journal of the American Chemical Society. ,vol. 90, pp. 4585- 4589 ,(1968) , 10.1021/JA01019A014
Karen M. Waltz, Clare N. Muhoro, John F. Hartwig, C−H Activation and Functionalization of Unsaturated Hydrocarbons by Transition-Metal Boryl Complexes Organometallics. ,vol. 18, pp. 3383- 3393 ,(1999) , 10.1021/OM990113V
Holger Braunschweig, Carsten Kollann, Daniela Rais, Transition-Metal Complexes of Boron—New Insights and Novel Coordination Modes Angewandte Chemie International Edition. ,vol. 45, pp. 5254- 5274 ,(2006) , 10.1002/ANIE.200600506
Holger Braunschweig, Carsten Kollann, Ulli Englert, Synthesis and Structure of the First Terminal Borylene Complexes Angewandte Chemie International Edition. ,vol. 37, pp. 3179- 3180 ,(1998) , 10.1002/(SICI)1521-3773(19981204)37:22<3179::AID-ANIE3179>3.0.CO;2-Z
Deborah L. Coombs, Simon Aldridge, Andrea Rossin, Cameron Jones, David J. Willock, Fe=B Double Bonds: Synthetic, Structural, and Reaction Chemistry of Cationic Terminal Borylene Complexes Organometallics. ,vol. 23, pp. 2911- 2926 ,(2004) , 10.1021/OM049793E
Yuichiro Kondo, Domingo García-Cuadrado, John F. Hartwig, Nicole K. Boaen, Nicole L. Wagner, Marc A. Hillmyer, Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. Journal of the American Chemical Society. ,vol. 124, pp. 1164- 1165 ,(2002) , 10.1021/JA016763J
Alan H Cowley, None, From group 13-group 13 donor-acceptor bonds to triple-decker cations. Chemical Communications. pp. 2369- 2375 ,(2004) , 10.1039/B409497M