Two components of Na emission in sonoluminescence spectrum from surfactant aqueous solutions.

作者: Yuichi Hayashi , Pak-Kon Choi

DOI: 10.1016/J.ULTSONCH.2014.07.012

关键词:

摘要: Abstract Sonoluminescence from sodium dodecyl sulfate (SDS) aqueous solutions exhibits Na emission. The spectrum of emission was measured as a function sonication time for total 30 min at an ultrasonic frequency 148 kHz. spectral line profiles changed with the time, suggesting that consists two components: broadened lines, which are shifted original D and unshifted narrow lines. intensity lines decreased greater rate than increasing time. This effect enhanced higher acoustic power. remained after 30 min. We propose these quenching effects caused by accumulation gases decomposed SDS molecules inside bubbles. CO 2 gas dependence in NaCl showed similar change to solutions, supported this proposition. easily affected foreign gases. results suggest components originate different environments around emitting species, although both them phase generation mechanisms discussed.

参考文章(30)
Pak-Kon Choi, Shogo Abe, Yuichi Hayashi, Sonoluminescence of Na Atom from NaCl Solutions Doped with Ethanol Journal of Physical Chemistry B. ,vol. 112, pp. 918- 922 ,(2008) , 10.1021/JP709661Z
Ritu Singla, Franz Grieser, Muthupandian Ashokkumar, The mechanism of sonochemical degradation of a cationic surfactant in aqueous solution Ultrasonics Sonochemistry. ,vol. 18, pp. 484- 488 ,(2011) , 10.1016/J.ULTSONCH.2010.09.013
Yuichi Hayashi, Pak-Kon Choi, Effects of alcohols on multi-bubble sonoluminescence spectra Ultrasonics. ,vol. 44, pp. e421- e425 ,(2006) , 10.1016/J.ULTRAS.2006.08.011
B. Yim, H. Okuno, Y. Nagata, R. Nishimura, Y. Maeda, Sonolysis of surfactants in aqueous solutions: an accumulation of solute in the interfacial region of the cavitation bubbles. Ultrasonics Sonochemistry. ,vol. 9, pp. 209- 213 ,(2002) , 10.1016/S1350-4177(01)00123-7
David J. Flannigan, Kenneth S. Suslick, Emission from electronically excited metal atoms during single-bubble Sonoluminescence. Physical Review Letters. ,vol. 99, pp. 134301- ,(2007) , 10.1103/PHYSREVLETT.99.134301
C. Sehgal, R. P. Steer, R. G. Sutherland, R. E. Verrall, Sonoluminescence of argon saturated alkali metal salt solutions as a probe of acoustic cavitation Journal of Chemical Physics. ,vol. 70, pp. 2242- 2248 ,(1979) , 10.1063/1.437704
Jingfeng Guan, Thomas J. Matula, Time scales for quenching single-bubble sonoluminescence in the presence of alcohols Journal of Physical Chemistry B. ,vol. 107, pp. 8917- 8921 ,(2003) , 10.1021/JP026494Z
Shogo Abe, Pak-Kon Choi, Spatiotemporal Separation of Na-Atom Emission from Continuum Emission in Sonoluminescence Japanese Journal of Applied Physics. ,vol. 48, ,(2009) , 10.1143/JJAP.48.07GH02
Judy Lee, Ivan U. Vakarelski, Kyuichi Yasui, Toru Tuziuti, Teruyuki Kozuka, Atsuya Towata, Yasuo Iida, Variations in the Spatial Distribution of Sonoluminescing Bubbles in the Presence of an Ionic Surfactant and Electrolyte Journal of Physical Chemistry B. ,vol. 114, pp. 2572- 2577 ,(2010) , 10.1021/JP907329Z