Trap level analysis of Ce3+ and Sm3+ in Li6Y(BO3)3

作者: D. Joseph Daniel , H.J. Kim , Sunghwan Kim , S. Kothan , J. Kaewkhao

DOI: 10.1016/J.CERAMINT.2019.03.072

关键词:

摘要: Abstract The polycrystalline compounds of Li6Y(BO3)3: Ce3+ and Sm3+ co-doped samples were prepared by using standard solid state reaction method. energy levels the doped lanthanide ions (Ce3+ Sm3+) in borate host materials investigated Thermoluminescence (TL) glow peak analysis. samples, exhibits TL at higher temperature region around 511 K whereas individually sample has 433 K. X-ray excited emission spectra carried out for all found characteristic bands. trap depths (E) calculated several methods, namely shape method or chen's (PS), variable heating rate (VHR), initial rise (IR) computerized curve deconvolution (CGCD). mean activation to be 1.21 (0.07±) eV frequency factor 1.38 × 1011 Sec−1. predicted level values compared good agreement. This primarily results suggest that scheme can help development new suitable dosimetry.

参考文章(25)
P Dorenbos, L Pierron, L Dinca, C W E van Eijk, A Kahn-Harari, B Viana, 4f?5d spectroscopy of Ce3+ in CaBPO5, LiCaPO4 and Li2CaSiO4 Journal of Physics: Condensed Matter. ,vol. 15, pp. 511- 520 ,(2003) , 10.1088/0953-8984/15/3/315
Andrei V. Sidorenko, Adrie J.J. Bos, Pieter Dorenbos, Carel W.E. van Eijk, Andrée Kahn-Harari, Piotr A. Rodnyi, Bruno Viana, Storage effect in LiRESiO4:Ce3+, Sm3+, RE=Y,Lu phosphor Nuclear Instruments & Methods in Physics Research Section A-accelerators Spectrometers Detectors and Associated Equipment. ,vol. 537, pp. 81- 85 ,(2005) , 10.1016/J.NIMA.2004.07.239
R.P. Yavetskiy, A.V. Tolmachev, E.F. Dolzhenkova, V.N. Baumer, Thermally stimulated luminescence mechanism of Li6Y(BO3)3:Eu3+ single crystals Journal of Alloys and Compounds. ,vol. 429, pp. 77- 81 ,(2007) , 10.1016/J.JALLCOM.2006.04.040
G Kitis, J W N Tuyn, A simple method to correct for the temperature lag in TL glow-curve measurements Journal of Physics D. ,vol. 31, pp. 2065- 2073 ,(1998) , 10.1088/0022-3727/31/16/017
G Kitis, J M Gomez-Ros, J W N Tuyn, Thermoluminescence glow-curve deconvolution functions for first, second and general orders of kinetics Journal of Physics D. ,vol. 31, pp. 2636- 2641 ,(1998) , 10.1088/0022-3727/31/19/037
A Sifi, R.S Klein, A Maillard, G.E Kugel, A Péter, K Polgár, Absolute non-linear optical coefficients measurements of CsLiB6O10 single crystals by second harmonic generation Optical Materials. ,vol. 24, pp. 431- 435 ,(2003) , 10.1016/S0925-3467(03)00160-5
Igor N Ogorodnikov, Nikita E Poryvay, Vladimir A Pustovarov, Radiation effects and defects in lithium borate crystals IOP Conference Series: Materials Science and Engineering. ,vol. 15, pp. 012016- ,(2010) , 10.1088/1757-899X/15/1/012016
Reuven Chen, Glow Curves with General Order Kinetics Journal of The Electrochemical Society. ,vol. 116, pp. 1254- 1257 ,(1969) , 10.1149/1.2412291
Zaiwei Fu, Shangke Pan, Fan Yang, Shenjie Gu, Xiangcui Lei, Yuekun Heng, Guohao Ren, Ming Qi, Neutron detection properties of Li6Y(BO3)3:Ce crystal Radiation Measurements. ,vol. 72, pp. 39- 43 ,(2015) , 10.1016/J.RADMEAS.2014.11.010
Yidong Huang, Chaoyang Tu, Zundu Luo, Guang Chen, Spectra and intensity parameters of Li6Y (BO3)3:Nd3+ laser crystal Optics Communications. ,vol. 92, pp. 57- 60 ,(1992) , 10.1016/0030-4018(92)90218-G