Survey reactivity of some N-aryl formamides with pentafluoropyridine

作者: Reza Ranjbar-Karimi , Alireza Poorfreidoni , Hamid Reza Masoodi

DOI: 10.1016/J.JFLUCHEM.2015.10.008

关键词:

摘要: Abstract Chemo selectivity of some N -aryl formamides with pentafluoropyridine under basic conditions in dry THF was investigated. The aromatic nucleophilic substitution enol–imines derived from occurs at the 4-position pyridine ring by both oxygen and nitrogen site depending on nature substituent; electron releasing group, attack accomplished atom an withdrawing reaction formamide anions proceeded via site.

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