Anomalously intense Raman scattering at the solid-electrolyte interface
作者： T.E. Furtak
DOI: 10.1016/0038-1098(78)90107-2
关键词:
摘要: Abstract The enhanced Raman effect is used to characterize cyanide on silver at the interface with 0.1 M Na 2 SO 4 + 0.01 KCN solution. We conclude bond polarized considerable backbonding. scattering intensity dependence electrode voltage supports enhancement models which involve wavefunction overlap between metal and adsorbate.
harvard.edu
elsevier.com
sci-hub.se 参考文章(17)
Llewellyn H. Jones, Inorganic vibrational spectroscopy ,(1971)
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
David L. Jeanmaire, Richard P. Van Duyne, Surface raman spectroelectrochemistry Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 84, pp. 1- 20 ,(1977) , 10.1016/S0022-0728(77)80224-6
G. Hagen, B. Simic Glavaski, E. Yeager, The Raman spectrum of an adsorbed species on electrode surface Journal of Electroanalytical Chemistry. ,vol. 88, pp. 269- 275 ,(1978) , 10.1016/S0022-0728(78)80274-5
A. Otto, Raman spectra of (CN) - adsorbed at a silver surface Surface Science. ,vol. 75, ,(1978) , 10.1016/0039-6028(78)90263-7
W.A. Kamitakahara, B.N. Brockhouse, Crystal dynamics of silver Physics Letters A. ,vol. 29, pp. 639- 640 ,(1969) , 10.1016/0375-9601(69)91142-6
B. Pettinger, U. Wenning, Raman spectra of pyridine adsorbed on silver (100) and (111) electrode surfaces Chemical Physics Letters. ,vol. 56, pp. 253- 257 ,(1978) , 10.1016/0009-2614(78)80233-4
J.A. Creighton, M.G. Albrecht, R.E. Hester, J.A.D. Matthew, The dependence of the intensity of Raman bands of pyridine at a silver electrode on the wavelength of excitation Chemical Physics Letters. ,vol. 55, pp. 55- 58 ,(1978) , 10.1016/0009-2614(78)85131-8
Michael R. Philpott, Effect of surface plasmons on transitions in molecules The Journal of Chemical Physics. ,vol. 62, pp. 1812- 1817 ,(1975) , 10.1063/1.430708
T.E. Furtak, Cyanide bonding on AG (110) investigated by electroreflectance Solid State Communications. ,vol. 23, pp. 373- 376 ,(1977) , 10.1016/0038-1098(77)90235-6