Electron-Transfer Oxidation Properties of Unsaturated Fatty Acids and Mechanistic Insight into Lipoxygenases
作者： Hironori Kitaguchi , Kei Ohkubo , Seiji Ogo , Shunichi Fukuzumi
DOI: 10.1021/JP054648F
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摘要: Rate constants of photoinduced electron-transfer oxidation unsaturated fatty acids with a series singlet excited states oxidants in acetonitrile at 298 K were examined and the resulting rate (ket) evaluated light free energy relationship electron transfer to determine one-electron potentials (Eox) intrinsic barrier transfer. The ket values linoleic acid are same as corresponding methyl linoleate, linolenic acid, arachidonic leading Eox value (1.76 V vs SCE), which is significantly lower than that oleic (2.03 SCE) indicated by smaller those other acids. radical cation produced from state o...
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