Photoluminescence Enhancement of CdSe Quantum Dots: A Case of Organogel–Nanoparticle Symbiosis

作者: Prashant D. Wadhavane , Raquel E. Galian , M. Angeles Izquierdo , Jordi Aguilera-Sigalat , Francisco Galindo

DOI: 10.1021/JA310508R

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摘要: Highly fluorescent organogels (QD–organogel), prepared by combining a pseudopeptidic macrocycle and different types of CdSe quantum dots (QDs), have been characterized using battery optical microscopic techniques. The results indicate that the presence QDs not only does disrupt supramolecular organization internal fibrillar network organogel to significant extent, but it also decreases critical concentration gelator needed form stable thermoreversible organogels. Regarding photophysical properties QDs, trends were observed depending on ZnS inorganic shell around core. Thus, while core–shell preserve their in medium, high moderate increase fluorescence intensity (up 528%) average lifetime 1.7), respectively, was for core embedded organogel. are relevant development luminescent organog...

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