Porous conducting membranes based on polypyrrole–PMMA composites

作者: Maziar Nikpour , Hassan Chaouk , Albert Mau , Dong Jun Chung , Gordon Wallace

DOI: 10.1016/S0379-6779(98)01486-6

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摘要: Abstract A series of porous membranes consisting polymethyl methacrylate (PMMA) and polypyrrole (PPy) were prepared using porogen leaching techniques. The liquid used was polypropylene glycol, molecular weight 775 (PPG-775) while sodium chloride powder as the solid porogen. pore structure asymmetrical characterised scanning electron microscopy (SEM) which demonstrated sizes ranging from 2 to 100 μm. permeability with either lysozyme (molecular weight=14,000) or bovine serum albumin (BSA, weight=67,000). little resistance passage water PPG-774 had limited lysozyme.

参考文章(21)
Maria Omastová, Stanislav Kosina, Jürgen Pionteck, Andreas Janke, Juraj Pavlinec, Electrical properties and stability of polypyrrole containing conducting polymer composites Synthetic Metals. ,vol. 81, pp. 49- 57 ,(1996) , 10.1016/0379-6779(96)80228-1
H. Zhao, W.E. Price, C.O. Too, G.G. Wallace, D. Zhou, Parameters influencing transport across conducting electroactive polymer-membranes Journal of Membrane Science. ,vol. 119, pp. 199- 212 ,(1996) , 10.1016/0376-7388(96)00130-5
Tomokazu Iyoda, Akira Ohtani, Kenichi Honda, Takeo Shimidzu, Diaphragmatic chemical polymerization of pyrrole in the Nafion film Macromolecules. ,vol. 23, pp. 1971- 1976 ,(1990) , 10.1021/MA00209A016
Sachin P. Khedkar, S. Radhakrishnan, Application of dip-coating process for depositing conducting polypyrrole films Thin Solid Films. ,vol. 303, pp. 167- 172 ,(1997) , 10.1016/S0040-6090(97)00133-8
Hsing Lin Wang, Jack E. Fernandez, Blends of polypyrrole and poly(vinyl alcohol) Macromolecules. ,vol. 26, pp. 3336- 3339 ,(1993) , 10.1021/MA00065A015
Eli Ruckenstein, Liang Hong, Inverted emulsion pathway to polypyrrole and polypyrrole elastomer composites Synthetic Metals. ,vol. 66, pp. 249- 256 ,(1994) , 10.1016/0379-6779(94)90074-4
Kensuke Kamada, Jun Kamo, Akira Motonaga, Tadashi Iwasaki, Hiroshi Hosokawa, Gas Permeation Properties of Conducting Polymer/Porous Media Composite Membranes II Polymer Journal. ,vol. 26, pp. 833- 839 ,(1994) , 10.1295/POLYMJ.26.833
D. Zhou, H. Zhao, W.E. Price, G.G. Wallace, Electrochemically controlled transport in a dual conducting polymer membrane system Journal of Membrane Science. ,vol. 98, pp. 173- 176 ,(1995) , 10.1016/0376-7388(94)00186-3
Paul Burgmayer, Royce W. Murray, An Ion Gate Membrane: Electrochemical Control of Ion Permeability through a Membrane with an Embedded Electrode Journal of the American Chemical Society. ,vol. 104, pp. 6139- 6140 ,(1982) , 10.1021/JA00386A061
C.J. Small, C.O. Too, G.G. Wallace, Responsive conducting polymer-hydrogel composites Polymer Gels and Networks. ,vol. 5, pp. 251- 265 ,(1997) , 10.1016/S0966-7822(96)00044-5