Synthesis, characterization, and MTO performance of MeAPSO-34 molecular sieves

作者: Lei Xu , Zhongmin Liu , Aiping Du , Yingxu Wei , Zhengang Sun

DOI: 10.1016/S0167-2991(04)80092-2

关键词:

摘要: MeAPSO-34 molecular sieves were synthesized successfully with metal ions of Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Mg, Ca, Sr, and Ba (Me/Al2O3=0.05). IR, NH3-TPD measurements fixed bed MTO performances all the samples carried out in comparison SAPO-34. The results illustrated that incorporation had great effects on structure acidity sieves. It was interesting most exhibited effective enhancement performance. Especially, Co2+, Zn2+ Mg2+ showed promising modification effect for catalysts.

参考文章(7)
S. Nawaz, S. Kolboe, S. Kvisle, K-P. Lillerud, M. Stocker, H.M. Øren, Selectivity and Deactivation Profiles of Zeolite Type Materials in the MTO Process Studies in Surface Science and Catalysis. ,vol. 61, pp. 421- 427 ,(1991) , 10.1016/S0167-2991(08)60108-1
Brent M. Lok, Celeste A. Messina, R. Lyle Patton, Richard T. Gajek, Thomas R. Cannan, Edith M. Flanigen, Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids Journal of the American Chemical Society. ,vol. 106, pp. 6092- 6093 ,(1984) , 10.1021/JA00332A063
German Sastre, Dewi W. Lewis, C. Richard A. Catlow, Modeling of Silicon Substitution in SAPO-5 and SAPO-34 Molecular Sieves Journal of Physical Chemistry B. ,vol. 101, pp. 5249- 5262 ,(1997) , 10.1021/JP963736K
Tomoyuki Inui, Suphot Phatanasri, Hirokazu Matsuda, Highly selective synthesis of ethene from methanol on a novel nickel–silicoaluminophosphate catalyst Journal of The Chemical Society, Chemical Communications. pp. 205- 206 ,(1990) , 10.1039/C39900000205
Sunil Ashtekar, Satyanarayana V. V. Chilukuri, Dipak K. Chakrabarty, SMALL-PORE MOLECULAR-SIEVES SAPO-34 AND SAPO-44 WITH CHABAZITE STRUCTURE - A STUDY OF SILICON INCORPORATION The Journal of Physical Chemistry. ,vol. 98, pp. 4878- 4883 ,(1994) , 10.1021/J100069A018
J. M. Thomas, Y. Xu, C. R. A. Catlow, J. W. Couves, Synthesis and characterization of a catalytically active nickel silicoaluminophosphate catalyst for the conversion of methanol to ethene Chemistry of Materials. ,vol. 3, pp. 667- 672 ,(1991) , 10.1021/CM00016A020