A recyclable CO surrogate in regioselective alkoxycarbonylation of alkenes: indirect use of carbon dioxide.
作者： P. H. Gehrtz , V. Hirschbeck , I. Fleischer
DOI: 10.1039/C5CC05012J
关键词:
摘要: Herein, we report a Pd-catalysed alkoxycarbonylation of alkenes based on the use recyclable CO2 reduction product, crystalline and air-stable N-formylsaccharin, as CO surrogate. The carbonylation proceeds under ambient conditions in an exceptionally complementary regioselective fashion yielding desired branched products from styrene derivatives valuable linear esters alkyl-substituted alkenes.
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