Copper-catalyzed aerobic oxidation of alcohols under fluorous biphasic conditions
作者： Bodo Betzemeier , Marco Cavazzini , Silvio Quici , Paul Knochel
DOI: 10.1016/S0040-4039(00)00620-1
关键词:
摘要: A catalytic amount of perfluoroalkyl substituted bipyridine 1 (2 mol%), CuBr·Me2S mol%) and TEMPO (3.5 allow the oxidation various alcohols to aldehydes ketones in a fluorous biphasic system chlorobenzene perfluorooctane directly with oxygen. The catalyst can be used for several reaction runs without loss reactivity.
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