The role of the excited states in the photochemical behavior of ruthenocene in halocarbon solvents
作者： O. Traverso , S. Sostero , G.A. Mazzocchin
DOI: 10.1016/S0020-1693(00)93715-0
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摘要: Abstract Halocarbon solvents appears to form charge-transfer complexes with ruthenocene. Ruthenocene in halo-carbon exibits a new band of electron transfer solvent type at 285 nm. Irradiation by light, which excites the and not components, caused oxidation ruthenocene ruthenicenium cation. A possible mechanism thermal decomposition cation is discussed.
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