Hydrocarbons with Five Linearly Annellated Rings

作者: E. Clar

DOI: 10.1007/978-3-662-01665-7_24

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摘要: Pentacene was first obtained by dehydrogenation of dihydropentacene (V). This is formed pyrolysis the ketones (I), (II) and (III). Pentaphene (see p. 353) also produced as a by-product, sometimes even re-arrangement ketones. Dibenzoyl-m-xylene (I) prepared from xylene, benzoyl chloride aluminium under rather drastic conditions. The ketone terephthaloyl o-tolyl magnesium bromide (III) 4benzyl-1,3-dimethylbenzene, chloride.1

参考文章(2)
William J. Bailey, Chien-Wei Liao, Cyclic Dienes. XI. New Syntheses of Hexacene and Heptacene1,2 Journal of the American Chemical Society. ,vol. 77, pp. 992- 993 ,(1955) , 10.1021/JA01609A055