Studies in the basic mineralizing system, CaO-P2O5-H2O.
作者： H. Catherine W. Skinner
DOI: 10.1007/BF02060279
关键词:
摘要: Equilibrium phase diagrams have been determined for the system CaO-P2O5-H2 using hydrothermal synthesis techniques in temperature range 300–600° and 2 Kb H2O pressure. Well-crystallized hydroxyapatite has produced characterized. Small variations unit cell parameters dependent on of bulk composition starting materials determined. Precise chemical conditions were required to obtain apatite as only solid equilibrium with solution. diagram results are compared previous synthetic investigations.
springer.com
sci-hub.se 参考文章(22)
G. Trömel, H. Möller, Die Bildung schwer löslicher Calciumphosphate aus wäßriger Lösung und die Beziehungen dieser Phosphate zur Apatitgruppe Zeitschrift für anorganische und allgemeine Chemie. ,vol. 206, pp. 227- 240 ,(1932) , 10.1002/ZAAC.19322060212
G. M. Biggar, Experimental Studies of Apatite Crystallization in Parts of the System CaO-P2O5-H2O at 1000 Bars Mineralogical Magazine. ,vol. 36, pp. 1110- 1122 ,(1966) , 10.1180/MINMAG.1966.036.276.06
Henri Brasseur, Etude du phosphate tricalcique hydraté et de l'hydroxylapatite de synthèse par voie humide Bulletin des Sociétés Chimiques Belges. ,vol. 62, pp. 383- 400 ,(2010) , 10.1002/BSCB.19530620705
H. Catherine, W. Skinner, Transition of calcium orthophosphate to pyrophosphate at elevated pressures Materials Research Bulletin. ,vol. 5, pp. 437- 447 ,(1970) , 10.1016/0025-5408(70)90083-8
E. Hayek, F. M�llner, K. Koller, Zur Kenntnis des Hydroxylapatits Monatshefte Fur Chemie. ,vol. 82, pp. 959- 969 ,(1951) , 10.1007/BF00899373
Aaron S. Posner, Samuel R. Stephenson, Crystallographic investigation of tricalcium phosphate hydrate. Journal of Dental Research. ,vol. 31, pp. 371- 382 ,(1951) , 10.1177/00220345520310031501
Henry Bassett, 601. The phosphates of calcium. Part V. Revision of the earlier space diagram Journal of the Chemical Society (Resumed). pp. 2949- 2955 ,(1958) , 10.1039/JR9580002949
A. G. Cockbain, The Crystal Chemistry of the Apatites Mineralogical Magazine. ,vol. 36, pp. 654- 660 ,(1968) , 10.1180/MINMAG.1968.036.281.07
A. S. Posner, A. Perloff, A. F. Diorio, Refinement of the hydroxyapatite structure Acta Crystallographica. ,vol. 11, pp. 308- 309 ,(1958) , 10.1107/S0365110X58000815
Duncan McConnell, The stoichiometry of hydroxyapatite Naturwissenschaften. ,vol. 47, pp. 227- 227 ,(1960) , 10.1007/BF00602760