Analysis of the experimental orientation dependence of the reaction CH3I+Rb→RbI+CH3
作者： Richard B. Bernstein
DOI: 10.1063/1.448953
关键词:
摘要: Experiments by Parker et al. (1981), deconvoluted for the precession effect Stolte (1982), yielded dependence of reaction probability upon ‘‘angle attack’’ γ CH3I+ Rb reaction. Inversion these results is carried out via kinetic theory model reactive collisions rigid nonspherical molecules Evans (1985), yielding angle activation barrier as well an estimate colliding‐pair anisotropy (asphericity) parameter.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(18)
N. C. Blais, Richard B. Bernstein, R. D. Levine, Orientation dependence of the atomic hydrogen + molecular deuterium reaction cross section: steric model vs. trajectory calculations The Journal of Physical Chemistry. ,vol. 89, pp. 10- 13 ,(1985) , 10.1021/J100247A005
Philip R. Brooks, Eugene M. Jones, Reactive Scattering of K Atoms from Oriented CH3I Molecules The Journal of Chemical Physics. ,vol. 45, pp. 3449- 3450 ,(1966) , 10.1063/1.1728128
R.D. Levine, R.B. Bernstein, Opacity analysis of steric requirements in elementary chemical reactions Chemical Physics Letters. ,vol. 105, pp. 467- 471 ,(1984) , 10.1016/0009-2614(84)80092-5
Robert J. Beuhler, Richard B. Bernstein, Karl H. Kramer, Observation of the Reactive Asymmetry of Methyl Iodide. Crossed Beam Study of the Reaction of Rubidium with Oriented Methyl Iodide Molecules Journal of the American Chemical Society. ,vol. 88, pp. 5331- 5332 ,(1966) , 10.1021/JA00974A059
Glenn T. Evans, Richard S. C. She, Richard B. Bernstein, A simple kinetic theory model of reactive collisions of rigid nonspherical molecules Journal of Chemical Physics. ,vol. 82, pp. 2258- 2266 ,(1985) , 10.1063/1.448320
Y.M. Engel, R.D. Levine, Information content analysis for reaction of oreinted molecules Chemical Physics. ,vol. 91, pp. 167- 171 ,(1984) , 10.1016/0301-0104(84)80052-X
R.A. Labudde, P.J. Kuntz, R.B. Bernstein, R.D. Levine, Classical trajectory calculation of the energy dependence of the total reaction cross section for K + CH3I → KI + CH3 Chemical Physics Letters. ,vol. 19, pp. 7- 10 ,(1973) , 10.1016/0009-2614(73)87049-6
Ernesto E. Marinero, Charles T. Rettner, R. N. Zare, H+D2 reaction dynamics. Determination of the product state distributions at a collision energy of 1.3 eV Journal of Chemical Physics. ,vol. 80, pp. 4142- 4156 ,(1984) , 10.1063/1.447242
D.H. Parker, K.K. Chakravorty, R.B. Bernstein, Crossed beam reaction of oriented methyl iodide with rubidium: Steric factor and reactive asymmetry versus scattering angle Chemical Physics Letters. ,vol. 86, pp. 113- 117 ,(1982) , 10.1016/0009-2614(82)83251-X
K. H. Kramer, R. B. Bernstein, Focusing and Orientation of Symmetric‐Top Molecules with the Electric Six‐Pole Field The Journal of Chemical Physics. ,vol. 42, pp. 767- 770 ,(1965) , 10.1063/1.1696004