Synthesis, structure, and properties of a new 3D hydrogen-bonded porous coordination polymer
作者： J. W. Ji , Z. B. Han
DOI: 10.1134/S1070328410010069
关键词:
摘要: A new coordination polymer, [Cd(HMal)(Bipy)(H2O) · 2H2O (I) (H3Mal is malic acid, Bipy 4,4′-bipyridine), has been synthesized from H3Mal and under hydrothermal conditions characterized by elemental analysis, IR, TG, single-crystal X-ray diffraction. The diffraction analysis reveals that I (C14H16N2O7Cd) crystallizes in the orthorhombic system, space group Ibam. adjacent cadmium(II) atoms were first interconnected HMal ligands via carboxylate oxygen its hydroxyl to generate an infinite zigzag [Cd(HMal)]n chain, which are further linked form a 2D wavelike layer. Interestingly, layers connected hydrogen bonds, giving rise 3D porous framework with cross-sectional area of 11.690 × 9.326 A2. unit cell parameters for I: = 8,457(1), b 22.030(7), c 23.066(7) V 4297(2) A3, Z 4.
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