Fumed silica as a filler for MUPF resin in the process of manufacturing water-resistant plywood

作者: Dorota Dukarska , Rafał Czarnecki

DOI: 10.1007/S00107-015-0955-4

关键词:

摘要: This work examines the effect of applying fumed silica with nanoscopic-size particles as a filling material for melamine-urea-phenol-formaldehyde (MUPF) resin in process manufacturing water-resistant plywood. Moreover, this paper investigates possibility reducing amount MUPF mixture used gluing veneer sheets. Based on investigations into reactivity, viscosity and durability containing various amounts nanofiller, it was found that optimum can make suitable sheets to 2 PBW per 100 resin. The properties thus mixed were determined by measuring contact angle determining parameters its derivatives, which are an additional criterion evaluating properties. thermal stability tested simultaneous use TG–DSC analysis. experimental plywood manufactured using optimal nano-SiO2 terms bond quality mechanical according appropriate standards. prove is possible apply Introducing above-mentioned makes increase activation energy cross-linking optimize veneer. also produce required water-resistance adhesive reduced 30 %.

参考文章(39)
T. Sellers, Diisocyanate/furfural adhesive for bonding plywood Forest Products Journal. ,vol. 39, pp. 53- 56 ,(1989)
T. Jesionowski, J. Żurawska, A. Krysztafkiewicz, Surface properties and dispersion behaviour of precipitated silicas Journal of Materials Science. ,vol. 37, pp. 1621- 1633 ,(2002) , 10.1023/A:1014936428636
J. Łecka, D. Dukarska, The effect of an addition of TiO2 and SiO2 nanomolecules to phenolic resin on properties and colour of glue lines in exterior plywood. Annals of Warsaw University of Life Sciences - SGGW. Forestry and Wood Technology. ,vol. 68, pp. 198- 202 ,(2009)
S. Proszyk, Investigation of the durability of filled urea-formaldehyde adhesives against selected mould fungi. Material Und Organismen. ,vol. 25, pp. 123- 133 ,(1990)
Audrey Bonnefond, Yury Reyes, Pablo Peruzzo, Erik Ronne, Joanna Fare, Maria Paulis, Jose Ramon Leiza, Effect of the Incorporation of Modified Silicas on the Final Properties of Wood Adhesives Macromolecular Reaction Engineering. ,vol. 7, pp. 527- 537 ,(2013) , 10.1002/MREN.201300117
Herbert Barthel, Michael Dreyer, Torsten Gottschalk-Gaudig, Victor Litvinov, Ekaterina Nikitina, Fumed silica: Rheological additive for adhesives, resins, and paints Macromolecular Symposia. ,vol. 187, pp. 573- 584 ,(2002) , 10.1002/1521-3900(200209)187:1<573::AID-MASY573>3.0.CO;2-1
Jinshu Shi, Jianzhang Li, Wenrui Zhou, Derong Zhang, Improvement of wood properties by urea-formaldehyde resin and nano-SiO2 Frontiers of Forestry in China. ,vol. 2, pp. 104- 109 ,(2007) , 10.1007/S11461-007-0017-0
H. E. Kissinger, Reaction Kinetics in Differential Thermal Analysis Analytical Chemistry. ,vol. 29, pp. 1702- 1706 ,(1957) , 10.1021/AC60131A045
Zhenjiong Wang, Zhengbiao Gu, Yan Hong, Li Cheng, Zhaofeng Li, Bonding strength and water resistance of starch-based wood adhesive improved by silica nanoparticles Carbohydrate Polymers. ,vol. 86, pp. 72- 76 ,(2011) , 10.1016/J.CARBPOL.2011.04.003