Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles
作者： Victor M. Tormyshev , Olga Yu. Rogozhnikova , Michael K. Bowman , Dmitry V. Trukhin , Tatiana I. Troitskaya
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摘要: C-, N-, P-, and S-nucleophiles reacted with symmetrical tris(2,3,5,6-tetrathiaaryl)methyl cations, generated from the corresponding triarylmethanols by strong acids, to give a variety of asymmetrical monosubstituted persistent triaryl-methyl (TAM) radicals as major products. The only byproducts were TAMs.
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