Submillimeter resolved transient techniques for polymer electrolyte membrane fuel cell characterization: local in situ diagnostics for channel and land areas

作者: I.A. Schneider , M.H. Bayer , S. Von Dahlen

DOI: 10.1533/9780857095480.3.353

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摘要: Abstract: Key results of submillimeter resolved local in situ diagnostics channel and land areas polymer electrolyte fuel cells (PEFCs) are presented. Cyclic voltammetry (CV) electrochemical impedance spectroscopy (EIS) employed with resolution to demonstrate how lateral inhomogeneities affect the value electrochemically available surface area as obtained from CV experiments their contribution can lead misinterpretation EIS results. The correlation between liquid water accumulation cell performance is demonstrated by using simultaneous current density distribution measurement in-plane neutron radiography transient experiments. Finally, reverse phenomenon assessed during start-up shutdown a PEFC.

参考文章(106)
Denis Kramer, Jianbo Zhang, Ryoichi Shimoi, Eberhard Lehmann, Alexander Wokaun, Kazuhiko Shinohara, Günther G. Scherer, In situ diagnostic of two-phase flow phenomena in polymer electrolyte fuel cells by neutron imaging: Part A. Experimental, data treatment, and quantification Electrochimica Acta. ,vol. 50, pp. 2603- 2614 ,(2005) , 10.1016/J.ELECTACTA.2004.11.005
S. J. C. Cleghorn, C. R. Derouin, M. S. Wilson, S. Gottesfeld, A printed circuit board approach to measuring current distribution in a fuel cell Journal of Applied Electrochemistry. ,vol. 28, pp. 663- 672 ,(1998) , 10.1023/A:1003206513954
Jianbo Zhang, Denis Kramer, Ryoichi Shimoi, Yoshitaka Ono, Eberhard Lehmann, Alexander Wokaun, Kazuhiko Shinohara, Günther G. Scherer, In situ diagnostic of two-phase flow phenomena in polymer electrolyte fuel cells by neutron imaging Electrochimica Acta. ,vol. 51, pp. 2715- 2727 ,(2006) , 10.1016/J.ELECTACTA.2005.08.010
Mike L. Perry, Robert M. Darling, Shampa Kandoi, Timothy W. Patterson, Carl Reiser, Operating Requirements for Durable Polymer-Electrolyte Fuel Cell Stacks Springer, New York, NY. pp. 399- 417 ,(2009) , 10.1007/978-0-387-85536-3_20
Thomas J. Schmidt, High-Temperature Polymer Electrolyte Fuel Cells: Durability Insights Springer, New York, NY. pp. 199- 221 ,(2009) , 10.1007/978-0-387-85536-3_9
S. S. Kocha, Principles of MEA preparation Handbook of Fuel Cells. ,vol. 3, pp. 538- 565 ,(2010) , 10.1002/9780470974001.F303047
Michael A. Hickner, Daniel S. Hussey, Neutron Radioscopy: Industrial and Scientific Applications Encyclopedia of Analytical Chemistry. ,(2010) , 10.1002/9780470027318.A9069
Mathias Reum, Stefan A. Freunberger, Alexander Wokaun, Felix N. Büchi, Measuring the Current Distribution with Sub-Millimeter Resolution in PEFCs II. Impact of Operating Parameters Journal of The Electrochemical Society. ,vol. 156, ,(2009) , 10.1149/1.3043422
I. A. Schneider, S. A. Freunberger, D. Kramer, A. Wokaun, G. G. Scherer, Oscillations in gas channels. Part I. The forgotten player in impedance spectroscopy in PEFCs Journal of The Electrochemical Society. ,vol. 154, ,(2007) , 10.1149/1.2435706